Difference between revisions of "Machine phase"

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== Definitions ==
  
'''Molecules atoms moieties and molecular machine elements like [[diamondoid molecular elements|DMEs]]''' are said to be '''in the machine phase when''' they are '''fixated to a place or fixated to controlled axes''' (controlled degrees of freedome) such that [[thermal movement]] can't move them to unknown places or bring them in an unknown states.
+
=== Definition from the book [[Nanosystems]] ===
 +
 
 +
Citing 1:1 unchanged Section 1.1.2. a. Machine-phase systems.
 +
* A machine-phase system is one in which all atoms follow controlled trajectories (within a range determined in part by thermal excitation)
 +
* [[Machine-phase chemistry]] describes the chemical behaviour of machine-phase systems, in which all potentially reactive moieties follow controlled trajectories.
 +
 
 +
=== Definition for this wiki ===
 +
 
 +
Something is said to be '''in the machine phase when''' it is <br>
 +
'''fixated to a place or fixated to controlled axes''' (controlled degrees of freedom) such that <br>
 +
[[thermal motion]] (or at larger scales shaking) can't move them to unknown places or bring them into an unknown states. <br>
 +
Related: [[Tracing trajectories of component in machine phase]].
 +
 
 +
That something may be …
 +
* molecules, atoms, [[Moiety|moieties]] and larger:
 +
* molecular machine elements like [[diamondoid crystolecular machine element]]s ([[gemstone-like molecular element]]s)
 +
 
 +
So in [[Main Page|this wiki]] the definition for usage of "machine phase" may be a bit wider not only focusing on the atomic scale. <br>
 +
It can be a bit weird to talk about machine phase in the context of macroscale robotic systems. <br>
 +
But it may also provide new insights from a change in perspective.
 +
 
 +
== Why work in the machine phase? ==
 +
 
 +
=== The natural solution to the problem of assemblying products ===
 +
 
 +
For the problem of assembling stuff in an efficient fast and controlled ways macroscale robotics is just a natural choice. <br>
 +
And as it turns out almost [[macroscale style machinery at the nanoscale]] works even better at the nanoscale that at the macroscale. <br>
 +
<small>(Contrary to what the [[effects of current day experimental research limitations]] may seem to imply)</small>
 +
 
 +
Macroscale "cog-and-gear machinery" is typically in an eutactic phase. <br>
 +
Well there are a few exceptions where a bit of macroscale dystactic phase is involved. <br>
 +
Like e.g. part rattlers forcing parts in the right orientation.
 +
 
 +
==== Related notes ====
 +
 
 +
Nanoscale [[crystolecules]] will be hard to even get off of a crystolecular robotic nanomachinery gripper due to the [[Van der Waals force]] being significant. <br>
 +
But once off of an robotic gripper and on onto a perfectly flat surface (with mismatching atomic corrugations) <br>
 +
then they may [[superlubricity|superlubricatingly]] skitter around till the get stuck in a random nearby corner. <br>
 +
See: [[Intuitive feel#Everything is shaky]]
 +
 
 +
Releasing single small molecules from eutactic phase to [[dystactic phase]] is easier than releasing whole [[crystolecules]] which are much bigger (thousands of atoms typically). <br>
 +
This is due to [[Van der Waals force]] binding them to the walls being much smaller. So small that it is usually overpowered by the [[characteristic thermal energy]] at room temperature. <br>
 +
 
 +
In fact in some sense [[PPV]] is an eutactic phase since all about it is known. We know that it is just completely empty. Ignoring virual particles cosmic rays and such here. <br>
 +
And in some sense the first released small gas molecule into that [[PPV]] replaces that [[PPV]] with the the positionally unknown and/or quantum dispersed presence of itself. <br>
 +
Creating a [[dystactic phase]]. The (intentionally or not) released gas molecule will not stop ballistically bouncing around until it eventually hits an open radical that binds strong enough to not let it go again.
 +
 
 +
An accidentally into a [[mechanosynthesis core]] released gas molecule may end up on a tooltip. Eventually leading to errors in the process of [[mechanosynthesis]]. <br>
 +
While accidental gas release can be made very unlikely it's also easily possible to expose plenty of alternative open radical binding sites. <br>
 +
See: [[Getter grid]]
 +
 
 +
=== Open loop control – Remember where you put your stuff when you operate blindly ===
  
 
Since assembly at the nanocosm is done blindly it is important to know where you left your things.
 
Since assembly at the nanocosm is done blindly it is important to know where you left your things.
 
Thus one wants to work in the machine phase.
 
Thus one wants to work in the machine phase.
 
Searching and grabbing your tools like we do in the makro world does not work.  
 
Searching and grabbing your tools like we do in the makro world does not work.  
Once one let go of a smaller molecule its as good as impossible to catch it again by grabbing it sterically (meaning with shape not chemical reactivity) one can imagine this as the molecule being supersleazy and superfast. As a sidenote: Light isn't usable at the nanocosm it has either too long wavelength or it's too energetic and needs too big generation and sensing facilities that are beyond simple nanomechanics.
+
Once one let go of a smaller molecule its as good as impossible to catch it again by grabbing it sterically (meaning with shape not chemical reactivity) one can imagine this as the molecule being supersleazy and superfast.  
  
'''Performing chemistry in machine phase''' it is called '''machine phase chemistry or [[mechanosynthesis]]'''.
+
As a sidenote: A light based "nano-camera" isn't possible. <br>
It greatly accelerate reactions rates (compensating lower densities of reaction sites) and one obviously can freely choose where one wants each reaction to occur.
+
Light has either too long wavelength or it's too energetic and needs too big generation and sensing facilities that are beyond simple nanomechanics.
 +
 
 +
Main page: [[Open loop control]]
 +
 
 +
=== Energy efficiency ===
 +
 
 +
It's also a matter of energy efficiency.
 +
Catching a particle from [[dystactic phase]] into eutactic phase can "squeeze out" a thermal degree of freedom
 +
that contained (according to the [[equipartitioning theorem]]) an energy of k<sub>B</sub>T.
 +
Even if that is kept as reversible as possible that energy turnover causes unnecessary losses.
 +
* dystactic to eutactic catching – DOFs are queezed out – heating
 +
* eutactiic to dystactic releasing – DOFs fill up – cooling
 +
Related: [[entropomechanical converters]] and [[diamondoid heat pump]]s. There this is done on purpouse.
 +
 
 +
Furthermore some [[dystatic phases]] (liquid and gas phase) also impose viscous drag. <br>
 +
That is in the case of when speeds are enforced are above the (typically quite low) natural diffusion speeds.
 +
 
 +
== Machine phase chemistry ==
 +
 
 +
'''See main page: [[Machine-phase chemistry]].'''
 +
 
 +
Performing chemistry in machine phase it is called [[machine-phase chemistry]] which includes [[mechanosynthesis]]. <br>
 +
It greatly accelerates reactions rates (compensating lower densities of reaction sites) and one obviously can freely choose where one wants each reaction to occur. Site picking [[specificity]].
 +
 
 +
* [[Nanosystems]] 1.2.2.a '''Machine-phase chemistry describes the chemical behavior of machine-phase systems, in which all potentially reactive [[Moiety|moieties]] follow controlled trajectories.'''
 +
 
 +
== Partial machine phase in biological and diamondoid systems ==
  
 
When a [[diamondoid molecular elements|DMME bearing]] is fixed on an axle but freely allowed to rotate one can think of this as the bearing being only partly in the machine phase.
 
When a [[diamondoid molecular elements|DMME bearing]] is fixed on an axle but freely allowed to rotate one can think of this as the bearing being only partly in the machine phase.
 
Though not in a strong sense biological systems sometimes operate in machine phase too.
 
Though not in a strong sense biological systems sometimes operate in machine phase too.
 
Enzymes binding two reactants at the same time and acting like a vibrating hinge (like chattering teeth) that repeatedly bring the reactants together
 
Enzymes binding two reactants at the same time and acting like a vibrating hinge (like chattering teeth) that repeatedly bring the reactants together
can dramatically icrease reaction rates. This is often described as an increase of [http://metamodern.com/2009/03/22/effective-concentration-in-self-assembly-catalysis-and-mechanosynthesis/ ''effective concentration''].
+
can dramatically increase reaction rates. This is often described as an increase of [https://web.archive.org/web/20160320141005/http://metamodern.com/2009/03/22/effective-concentration-in-self-assembly-catalysis-and-mechanosynthesis/ ''effective concentration'' (waybackmachine)] [http://metamodern.com/2009/03/22/effective-concentration-in-self-assembly-catalysis-and-mechanosynthesis/ (direct link dead)].
  
 
In the step from [[technology level 0]] to [[technology level I]] bigger purely self assembled sturdy structures may start to provide local machine phase.
 
In the step from [[technology level 0]] to [[technology level I]] bigger purely self assembled sturdy structures may start to provide local machine phase.
 +
 +
== Alternate terminology ==
 +
 +
Similar more or less overlapping in in meaning to machine phase
 +
* eutactic phase
 +
* positive control
 +
 +
Machine phase is sometimes also called '''"eutactic phase"'''. Eutactic means "well ordered". <br>
 +
I would advise against using this term though as it is easy to confuse with eutectic.<br>
 +
<small>Eutectic means "well melting" in thermodynamic equilibrium material science. Pretty much the opposite.</small>
 +
 +
Machine phase is tightly linked to '''[[digital control over matter]]'''. <br>
 +
Both are about fully determinitsic systems with all system internal states known at all times.
 +
 +
== External Links ==
 +
 +
* [http://e-drexler.com/d/06/00/Nanosystems/ch1/chapter1_3.html Nanosystems 1.2.2a]
 +
----
 +
* Positive control mentioned here in context of continuous motion factory automation: https://youtu.be/eGFS4eW4Vn8?t=62
 +
* "Positive locking" definition: https://fsae.engineering.columbia.edu/FSAE_Rules_2021_V1_files/part246.htm
 +
* [https://en.wikipedia.org/wiki/Positive_locking_device Positive locking device]
 +
* [https://en.wikipedia.org/wiki/Positive_displacement Positive displacement] pump/meter/pipette/...?
 +
 +
== Related ==
 +
 +
* '''[[Open loop control]]'''
 +
* [[Stiffness]] & [[Mechanosynthesis]]
 +
* solid state
 +
* forced condensation (molecule pick-up into machine phase)
 +
* [[Mobility prevention guideline]]
 +
* [[Trapped free particle]]
 +
* Machine phase is also called '''eutactic phase''' so the opposite is here called '''[[dystactic phase]]'''
 +
* '''[[Tracing trajectories of component in machine phase]]'''
 +
----
 +
* [[self centering]]
 +
* [[Digital control over matter]] (not [[digital fabrication]])
 +
* [[materializable programs]], [[programmable materials]]
 +
----
 +
* [[positional assembly]] (sometimes also called stereotactic assembly)
 +
----
 +
* '''[[Dystactic phase]]'''
 +
 +
[[Category:General]]

Latest revision as of 12:42, 11 February 2024

Definitions

Definition from the book Nanosystems

Citing 1:1 unchanged Section 1.1.2. a. Machine-phase systems.

  • A machine-phase system is one in which all atoms follow controlled trajectories (within a range determined in part by thermal excitation)
  • Machine-phase chemistry describes the chemical behaviour of machine-phase systems, in which all potentially reactive moieties follow controlled trajectories.

Definition for this wiki

Something is said to be in the machine phase when it is
fixated to a place or fixated to controlled axes (controlled degrees of freedom) such that
thermal motion (or at larger scales shaking) can't move them to unknown places or bring them into an unknown states.
Related: Tracing trajectories of component in machine phase.

That something may be …

So in this wiki the definition for usage of "machine phase" may be a bit wider not only focusing on the atomic scale.
It can be a bit weird to talk about machine phase in the context of macroscale robotic systems.
But it may also provide new insights from a change in perspective.

Why work in the machine phase?

The natural solution to the problem of assemblying products

For the problem of assembling stuff in an efficient fast and controlled ways macroscale robotics is just a natural choice.
And as it turns out almost macroscale style machinery at the nanoscale works even better at the nanoscale that at the macroscale.
(Contrary to what the effects of current day experimental research limitations may seem to imply)

Macroscale "cog-and-gear machinery" is typically in an eutactic phase.
Well there are a few exceptions where a bit of macroscale dystactic phase is involved.
Like e.g. part rattlers forcing parts in the right orientation.

Related notes

Nanoscale crystolecules will be hard to even get off of a crystolecular robotic nanomachinery gripper due to the Van der Waals force being significant.
But once off of an robotic gripper and on onto a perfectly flat surface (with mismatching atomic corrugations)
then they may superlubricatingly skitter around till the get stuck in a random nearby corner.
See: Intuitive feel#Everything is shaky

Releasing single small molecules from eutactic phase to dystactic phase is easier than releasing whole crystolecules which are much bigger (thousands of atoms typically).
This is due to Van der Waals force binding them to the walls being much smaller. So small that it is usually overpowered by the characteristic thermal energy at room temperature.

In fact in some sense PPV is an eutactic phase since all about it is known. We know that it is just completely empty. Ignoring virual particles cosmic rays and such here.
And in some sense the first released small gas molecule into that PPV replaces that PPV with the the positionally unknown and/or quantum dispersed presence of itself.
Creating a dystactic phase. The (intentionally or not) released gas molecule will not stop ballistically bouncing around until it eventually hits an open radical that binds strong enough to not let it go again.

An accidentally into a mechanosynthesis core released gas molecule may end up on a tooltip. Eventually leading to errors in the process of mechanosynthesis.
While accidental gas release can be made very unlikely it's also easily possible to expose plenty of alternative open radical binding sites.
See: Getter grid

Open loop control – Remember where you put your stuff when you operate blindly

Since assembly at the nanocosm is done blindly it is important to know where you left your things. Thus one wants to work in the machine phase. Searching and grabbing your tools like we do in the makro world does not work. Once one let go of a smaller molecule its as good as impossible to catch it again by grabbing it sterically (meaning with shape not chemical reactivity) one can imagine this as the molecule being supersleazy and superfast.

As a sidenote: A light based "nano-camera" isn't possible.
Light has either too long wavelength or it's too energetic and needs too big generation and sensing facilities that are beyond simple nanomechanics.

Main page: Open loop control

Energy efficiency

It's also a matter of energy efficiency. Catching a particle from dystactic phase into eutactic phase can "squeeze out" a thermal degree of freedom that contained (according to the equipartitioning theorem) an energy of kBT. Even if that is kept as reversible as possible that energy turnover causes unnecessary losses.

  • dystactic to eutactic catching – DOFs are queezed out – heating
  • eutactiic to dystactic releasing – DOFs fill up – cooling

Related: entropomechanical converters and diamondoid heat pumps. There this is done on purpouse.

Furthermore some dystatic phases (liquid and gas phase) also impose viscous drag.
That is in the case of when speeds are enforced are above the (typically quite low) natural diffusion speeds.

Machine phase chemistry

See main page: Machine-phase chemistry.

Performing chemistry in machine phase it is called machine-phase chemistry which includes mechanosynthesis.
It greatly accelerates reactions rates (compensating lower densities of reaction sites) and one obviously can freely choose where one wants each reaction to occur. Site picking specificity.

  • Nanosystems 1.2.2.a Machine-phase chemistry describes the chemical behavior of machine-phase systems, in which all potentially reactive moieties follow controlled trajectories.

Partial machine phase in biological and diamondoid systems

When a DMME bearing is fixed on an axle but freely allowed to rotate one can think of this as the bearing being only partly in the machine phase. Though not in a strong sense biological systems sometimes operate in machine phase too. Enzymes binding two reactants at the same time and acting like a vibrating hinge (like chattering teeth) that repeatedly bring the reactants together can dramatically increase reaction rates. This is often described as an increase of effective concentration (waybackmachine) (direct link dead).

In the step from technology level 0 to technology level I bigger purely self assembled sturdy structures may start to provide local machine phase.

Alternate terminology

Similar more or less overlapping in in meaning to machine phase

  • eutactic phase
  • positive control

Machine phase is sometimes also called "eutactic phase". Eutactic means "well ordered".
I would advise against using this term though as it is easy to confuse with eutectic.
Eutectic means "well melting" in thermodynamic equilibrium material science. Pretty much the opposite.

Machine phase is tightly linked to digital control over matter.
Both are about fully determinitsic systems with all system internal states known at all times.

External Links


Related