Base materials with high potential

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Very good materials

Best of the best

All diamondoids come in:

  • cubic zincblende structure
  • hexagonal wurzite structure

Related main page: Diamond like compounds

Best diamondoid compounds

C – pure carbon "dialondeite" this includes the allotropes:

  • C in zincblende structure is called diamond of the normal cubic variety
  • C in wurzite structure is called lonsdaleite "hexagonal diamond"

SiC – gemstone quality optically transparent silicon carbide aka moissanite.
The structure of natural moissanite is in-between the zincblende and the wurzite structure.
This is part of what makes natural moissanite more though than natural diamond.
This does not apply to piezochemically mechanosynthesized and very small structures like some crystolecules though.
A main advantage of moissanite over diamond is it's high heat and oxidation resistance.

Si – pure silicon (eventually)
Not optically transparent since a semiconductor with low enough bandgap.
Lower mechanical chemical and thermal stability then the above.

BN – boron nitride (cubic c-BN and hexagonal w-BN)
Boron is not super extremely abundant and available
There is a rate natural mineral of this called – quingsongit (de) – cubic – Mohs 9-10

BC2N – heterodiamond
Basically an intermediate between dialondeite and quingsongit

AlN – aluminum nitride
A main advantage compared to boron nitride is that aluminium is much more common than boron.
Disadvantages are lower mechanical (thermal?) and chemical stability.
It is not stable against water, nanomachinery out of this material must be sealed.

Not diamond structure:
B4C – boron carbide High mechanical thermal and chemical resistance. Boron is not as common and almost everywhere accessible as carbon though.

Best SiO2 polymorphs

Metastable ultrahard and dense SiO2 polymorphs:

Simple titanium gemstones

Titanium combined with all sorts of abundant non-metal elements forms astoundingly many gemstone like compounds with exceptionally good mechanical and thermal properties. (Unlike the extremely abundant element iron that disappointingly underperforms in this regard). Titanium is reasonably abundant in Earths crust. Not as common as iron though. Titanium is especially common on our moon. There is also lack of non-volatile non-metal elements (like carbon and nitrogen) to combine it with though. Well, even for a quite big moonbases the volatiles in polar moon craters will suffice.

Titanium compounds with second row elements

  • TiB2 titanium diboride - hexagonal 2D layered - 3230°C - 4.52g/ccm - optically metallic - highly refractory compound
  • TiC titanium carbide - simple cubic - 3160°C (800°C in air) - 4.93g/ccm Mohs 9 to 9.5 - water insoluble (almost)
  • TiN titanium nitride - simple cubic - 2,947°C - 5.21 g/cm3 - optically metallic (golden) - "barrier metal" - water insoluble (almost)

Associated minerals:

Titanium oxides:

  • TiO [1] - hongquiite - simple cubic - 1,750C° - 4.95g/ccm - optically metallic (golden)
  • Ti2O3 [2] - tistarite - hexagonal corundum structure (like sapphire) - 2,130°C (decomposes) - 4.49g/ccm - semiconducting to metallic at 200°C
  • TiO2 [3] - rutile, anatase, brookite, and more

Titanium compounds with third row elements:

  • TiSi2 titanium disilicide - orthorhombic (complex unit cell) - 1,470°C - 4.02g/ccm - water insoluble - optically metallic and electrically conductive - More titanium silicides ...
  • Ti3Si - tetragonal - (isotype to Ti3P - see above and Zr3P)
  • Ti5Si4 - 2120°C - tetragonal (isotype to Zr5Si4)
  • TiSi titanium monosilicide - 1760 °C - orthorhombic (isotype to FeB)
  • Ti5Si9 - spacegroup Cmcm (Nr. 63) - 3.9g/ccm
  • Ti5Si3

Given silicon is a semi-metal and titanium is a metal titanium silicides should come with quite metallic properties (optically and electrically).
But mechanically still gemstone like like inter-metallic compounds.

Simple zirconium gemstones

Zirconium Zr compounds (maybe)

  • Zr (fifth row) is the element below Titanium (fourth row)
  • Zr is the most abundant fifth and below row non alkali element (Earth's crust).
  • Zr makes similarly good compounds with various other elements as Ti

Quite simple rutile structure & Hard

And neo-polymorphs with rutile structure. These include:

  • Silicon group: GeO2, SnO2, β-PbO2 – (germanium Ge is rather rare)
  • Other: MnO2, FeSbO4 – (antimony Sb is rather rare)

See: rutile structure. There is also a mention on that on the page about silicon
This could be called the the stishovite continuum or the rutile continuum'.

Corundum structure & hard

The corundum structure has lower symmetry than the rutile structure
which can be but not necessarily is a downside in that the design of crystolecules
based on these materials might be more difficult and or more limited.

  • Eskolatite (Cr2O3) – Mohs 8 – optically metallic – Chromium is less common
  • Hematite (Fe2O3) – Mohs 5.5 to 6.5 – optically metallic – Iron compounds are usually weaker

For more examples including less performant ones see:
Corundum structure – corundum is a term for low grade sapphire (and polymorphs: deltalumite)

Mono metal monoxides (simple cublic NaCl salt structure)

Earth alkali based

  • MgO periclase
  • CaO anhydrous lime - questionable - highly reactive with water - ok if well sealed inside of products

Transition metal based

Some transition metal monoxides (Typical: Max 1300-1900°C - Mohs 5-6)

  • TiO hongquiite
  • MnO manganosite - (Mn is less abundant)
  • FeO wüstite
  • NiO bunsenite - (Ni is not too abundant on earth but very abundant on metallic asteroids)

V vanadium, Cr chromium, Co cobalt do that too but
these elements are more scarce thus
not included as pure high volume base materials here

Other quite interesting compounds

Decently hard iron nitrides:

  • Fe4N Roaldite 3D structure (de) – cubic – Mohs 5.5-6.0 – (very simple crystal structure)
  • Fe9N4 Siderazot 3D structure (de) – triclinic – Mohs ?? – (not as complex as formula suggests)

Silicon oxynitride:

Corundum/sapphire polymorphs (See: Leukosapphire#Polymorphs):

  • Al2O3 Deltalumite (δ form of corundum, polymorph of sapphire) – tetragonal – Mohs ?? (likely quite hard) – [6]

Spinel minerals (they all have nice cubic unit cells)

  • Spinel MgAl2O4 – Mohs 7.5 to 8.0 – cubic
  • Ulvöspinel TiFe2O4 – Mohs 5.5 to 6.0 – optically metallic

Ambient pressure stable high pressure modificaions of olivine:

  • High pressure modification of iron olivine γ-Fe2SiO4: Ahrensite – [7] – (Mohs 6 – 4.26g/ccm)
  • High pressure modification of magnesium olivine Mg2SiO4: Ringwoodite – (Mohs ? – 3.9g/ccm)

Quite good materials with some hampering weakness(es)

Con: low crystal structure symmetry

Con: Somewhat soft materials

Saving graces: very common or acessible elements, some degradability, nature friendliness (common biomineral – sea shells)

  • CaCO3 calcite – trigonal – Mohs 3 (defining mineral)
  • CaCO3 aragonite – ortorhombic – Mohs 3.5-4.0 – (a bit harder and somewhat higher symmetry crystal structure)

Others

  • BeO brommelite [8] – excellent material – hexagonal – simple minimal unit cell (de) – very hard Mohs 9

Problems:

  • beryllium is quite scarce
  • beryllium is quite poisonous – it's can be quite well sealed in a macroscopic gemstone though – brommelite gemstone based nanomachinery: not so clear

Garnets

X3Y2(SiO4)3 the class of garnet gemstones [9] – typically hard Mohs 6.6-7.5 – and cubic – but big unit cell

  • Andradite – Ca3Fe2Si3O12 – iron but no aluminum garnet – HUGE unit cell 3D structure (de)
  • Almandine – Fe3Al2Si3O12 – iron and aluminum garnet
  • Pyrope – Mg3Al2Si3O12 – aluminum but no iron
  • Grossular – Ca3Al2Si3O12 – aluminum but no iron
  • Spessartine – Mn3Al2Si3O12 – (less abundant manganese)
  • Uvarovite – Ca3Cr2Si3O12 – (less abundant chromium – neither aluminum nor iron)

Wikipedia:

Related

External links

Wkipedia:

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