Difference between revisions of "Molecule fragment"

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* carbon disulfide CS<sub>2</sub> [http://en.wikipedia.org/wiki/Carbon_disulfide (wikipedia)] - soluble in ethanol - con: toxic
 
* carbon disulfide CS<sub>2</sub> [http://en.wikipedia.org/wiki/Carbon_disulfide (wikipedia)] - soluble in ethanol - con: toxic
 +
* carbonyl sulfide ([http://en.wikipedia.org/wiki/Carbonyl_sulfide wikipedia]) - con: toxic, carries less sulfur than carbon disulfide
 
* hydrogen sulfide H2S, sulfur dioxide SO2, sulfur trioxide SO3 - all too dangerous and toxic
 
* hydrogen sulfide H2S, sulfur dioxide SO2, sulfur trioxide SO3 - all too dangerous and toxic
 
* syn-Propanethial-S-oxide C3H6OS ([http://en.wikipedia.org/wiki/Syn-Propanethial-S-oxide wikipedia]) - irritant expelled by cut onions
 
* syn-Propanethial-S-oxide C3H6OS ([http://en.wikipedia.org/wiki/Syn-Propanethial-S-oxide wikipedia]) - irritant expelled by cut onions
* diallyl trisulfide C6H10S3 ([http://en.wikipedia.org/wiki/Diallyl_trisulfide wikipedia]) - main component of garlic oil
+
* diallyl trisulfide C6H10S3 ([http://en.wikipedia.org/wiki/Diallyl_trisulfide wikipedia]) - main component of garlic oil - con: carries lots of carbon and hydrogen
 
* dimethyl trisulfide C2H6S3 ([http://en.wikipedia.org/wiki/Dimethyl_trisulfide wikipedia])
 
* dimethyl trisulfide C2H6S3 ([http://en.wikipedia.org/wiki/Dimethyl_trisulfide wikipedia])
 
* thioacetic acid C2H4OS ([http://en.wikipedia.org/wiki/Thioacetic_acid wikipedia])
 
* thioacetic acid C2H4OS ([http://en.wikipedia.org/wiki/Thioacetic_acid wikipedia])

Revision as of 07:00, 29 March 2015

Moieties are the smallest building blocks handeded in the advanced mechanosynthesis of technology level III and II. When a simple resource molecule is picked up with an empty tooltip one always ends up with a few atoms on the tooltip. Some bonds need to be broken open to make it a reactive radical ready for deposition. It is generally not necessary to prepare the picked up molecule down until only one atom is left. That is in most cases one does not put down single atoms but small moieties (always bond molecules). Most often unused bonds are left hydrogen capped and and only one or two bonds are actively used - the one to the tooltip and the one to the workpiece. Hydrogen and oxygen with one and two bonds respectively are subject for single atomic deposition. The heavier elements of the same groups - the halogenes calcogenes - too.

simple respurce molecules

For mechanosynthesis of diamond ethyne C2H2 methane CH4 and traces of digermane Ge2H6 can be used. This has been toroughly analyzed.

Further molecules of prime interest are carbon dioxide CO2 water H2O and nitrogen gas N2. The capability of handling those allows for tapping the air as a resource for products that (almost) exclusively contain diamondoid molecular elements out of hydrogen carbon oxygen and nitrogen (HCON).

From the metals Aluminum and Titanium would be of interest.

Resource molecules for other elements should preferentially be non or at least low toxic and easy to handle.

  • for boron: B2H6 diborane is toxic and reacts with water to
    B(OH)3 boric acid which is pretty harmless and thus a better resource
  • for fluorine: SF6 sulfur hexafluoride very heavy pretty inert gas, soluble in ethanol
    the sulfur can be used ore disposed as diluted sulfuric acid
  • for aluminum: ?
  • for silicon: silicic acid self polymerizes and is thus not suitable
    SiH4 [1] seems better but it's quite toxic, higher silans tend to be explosive
  • for phosphorus: PH3 phosphine seems too toxic
    H3O4P phosphoric acid seems good
  • for chlorine: dissolved table salt NaCl - or diluted hydrochloric acid

Sources for sulfur

of main interest

  • ammonium sulfate (NH4)2SO4 (wikipedia) - pro: waste nitrogen can go to atmosphere, massively available - con: explosive in dry form
  • methylsulfonylmethane C2H6O2S- (wikipedia) - pro: non toxic - con: carries carbon too
  • sulfuric acid H2SO4 (wikipedia) - pro: massively available - con: acidity

maybe interesting

  • carbon disulfide CS2 (wikipedia) - soluble in ethanol - con: toxic
  • carbonyl sulfide (wikipedia) - con: toxic, carries less sulfur than carbon disulfide
  • hydrogen sulfide H2S, sulfur dioxide SO2, sulfur trioxide SO3 - all too dangerous and toxic
  • syn-Propanethial-S-oxide C3H6OS (wikipedia) - irritant expelled by cut onions
  • diallyl trisulfide C6H10S3 (wikipedia) - main component of garlic oil - con: carries lots of carbon and hydrogen
  • dimethyl trisulfide C2H6S3 (wikipedia)
  • thioacetic acid C2H4OS (wikipedia)
  • methanesulfonic acid CH3SO3H (wikipedia), (wikipedia)