Difference between revisions of "Salts of oxoacids"

Revision as of 13:54, 20 December 2015

The X-O-X bonds present in those compounds increase the space between the spacially linking X atoms. This lead to a lower density of bonds in cross sections inclusion of bigger voids thus higher porousity. Due to the porousness of these compounds it is harder to get the surfaces flat - figuratively like the surface of a pumice stone. It's impossible to get them as smooth as passivated diamond. [todo: investigate wheter supralubricating bearings can be constructed from these types of diamondoid compounds]

(wikipedia:oxoacid)

Silicates (& Quartz)

Not exactly a salt but related ...

Phosphate minerals

(wikipedia)

• Especially interesting: Hydoxy- Fluor- & Clorapatite Ca₅(PO₄)₃(F,Cl,OH) - (Mohs 5 defining mineral) - a biomineral [1]
• Lazulite (wikipedia) & Scorzalite (wikipedia) magnesium iron aluminium phosphates - (Mohs 5.5-6)
• Phosphophyllite (wikipedia) - zinc iron phosphate - rather soft (Mohs 3.5)
• Pb₅(PO₄)₃Cl pyromorphite (wikipedia) - relatively hard for a lead mineral (Mohs 3.5)
• Y(PO₄) Xenotime (wikipedia) - rare yttrium - high symmetry (tetragonal) - (Mohs 4.5)
• Al₂(PO₄)(OH)₃ augelite [2] Mohs 4-4.5
• FePO₄ heterosite Wikipedia:Heterosit(de) Mohs 4-4.5
• MnPO₄ purpurite [3] Mohs 4-5 (unabundant manganese)
• (MgFe)2PO4F magnesium and iron wagnerite [4] Mohs (?)
• FeAl2(PO₄)₂ anhydous iron scorzalite [5] Mohs 6
• MgAl2(PO₄)₂ anhydous magnesium scorzalite Mohs 6
• Zn₂Fe(PO₄)₂•4H₂O phosphophyllite [6] Mohs 3.5 (soft)

Carbonate minerals

(wikipedia - minerals) (wikipedia - artificial)

• Calcite & Aragonite - calcium
• Magnesite - magnesium
• Siderite - iron
• Smithsonite - zinc
• Malachite & Azurite - copper
• Rhodochrosite - manganese (rare)
• ...
• Mg₃Ca(CO₃)₄ huntite [7] Mohs 1-2 (very soft!)

Sulfate minerals

(wikipedia)

Sulfate minerals are generally rather soft with few exceptions.
One of the harder ones is brochantite (wikipedia) - (Mohs 3.5-4)

• CaSO₄ anhydrite [8] (decomposes slowly to hydroxyde gypsum)

Borate minerals

(wikipedia)

• Mg₃B₇O₁₃Cl Boracite (wikipedia) - (Mohs 7-7.5)
• Mn₃B₇O₁₃Cl Chambersite (wikipedia) - (Mohs 7)

• Al₆B₅O₁₅(F,OH)₃ Jeremejevite (wikipedia) - (Mohs 6.5-7.5)
• Mg₇(BO₃)₃(OH)₄Cl Karlite (wikipedia) - (Mohs 5½)
• Ca₂B₅SiO₉(OH)₅ Howlite (wikipedia) - soft (Mohs 3.5)
• MnSn(BO₃)₂ Tusionite (wikipedia) - (Mohs 5-6) - tin
• CaZrAl₉O₁₅(BO₃) Painite (wikipedia) - rare zirconium (Mohs 8)
• ...

Nitrate Aluminate and other minerals

All rather water soluble. See: (wikipedia - minerals) (wikipedia - artificial)

Aluminates: (wikipedia)

External links

• Solubility chart: https://en.wikipedia.org/wiki/Solubility_chart