Difference between revisions of "Organic gemstone-like compound"

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{{site specific term}}
 
{{site specific term}}
 
 
'''Organic gemstones''' shall include all gemstones that ...
 
'''Organic gemstones''' shall include all gemstones that ...
 
* ... do not contain metals but only light non-metallic elements
 
* ... do not contain metals but only light non-metallic elements
 
* ... do contain carbon
 
* ... do contain carbon
  
Typically These ...
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'''Organic gemstones''' typically ...
 
* ... contain [[volatile elements]] (carbon, nitrogen)
 
* ... contain [[volatile elements]] (carbon, nitrogen)
 
* ... are combustible.
 
* ... are combustible.
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As always on this wiki: The heavier more scarce elements (Arsenic, Selenium, ...) are excluded for materials for eventual large scale structural use.
 
As always on this wiki: The heavier more scarce elements (Arsenic, Selenium, ...) are excluded for materials for eventual large scale structural use.
  
* [[Diamond]]
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* C [[Diamond]]
* [[Lonsdaleite]]
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* C [[Lonsdaleite]]
* [[Beta Carbon Nitride]] – (possibly a fire hazard)
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* β-C<sub>3</sub>N<sub>4</sub> [[Beta carbon nitride]] – (possibly a fire hazard)
* Stretching it a bit [https://en.wikipedia.org/wiki/Boron_carbides Boron carbides] like [https://en.wikipedia.org/wiki/Boron_carbide Terraboron monocarbide]
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* C<sub>?</sub>P<sub>?</sub> Likely some carbon phosphides (at least sheets) – eventual health hazard due to direct carbon phosphorus bonds (common in toxins)
* Likely some carbon phosphides (at least sheets) – eventual health hazard due to direct carbon phosphorus bonds (common in toxins)
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----
 +
Perhaps over(?)stretching it a bit: <br>
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* SiC Silicon carbide aka [[moissanite]]
 +
And [https://en.wikipedia.org/wiki/Boron_carbides boron carbides] like:
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* B<sub>4</sub>C [https://en.wikipedia.org/wiki/Boron_carbide Terraboron monocarbide]
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----
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* '''Metal carbides are NOT included here.''' <br>So e.g. titanium carbide (TiC) is NOT counted as organic gemstone-like compound here. <br> For these see: [[Simple metal containing carbides and nitrides]]
  
 
=== Why adding oxygen or sulfur only works for trace amounts ===
 
=== Why adding oxygen or sulfur only works for trace amounts ===
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but activation energies are low making these compounds into dangerous high energy explosives.
 
but activation energies are low making these compounds into dangerous high energy explosives.
  
== Dropping the condition on containing carbon ==
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== Related ==
 
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Including compounds without carbon one gets the <br>
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slightly bigger class of [[metal free gemstone-like compounds]]. <br>
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These include:
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* BN [[Boron nitride]] – likely incombustible
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* BP [[Boron phosphide]] – incombustible
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=== Adding sulfur – This time it works – somewhat ===
+
 
+
Adding a sulfur into the mix in high ratio does not make the metal and carbon free gemstones unstable (decomposing to gasses) immediately <br>
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but does instead lead some [[oddball compound|quite exotic stuff]] crossing over to polymeric nature:''' <br>
+
  
* B<sub>2</sub>S<sub>3</sub> Boron sulfide [https://en.wikipedia.org/wiki/Boron_sulfide (wikipedia)]
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* Superclass: [[Metal free gemstone-like compound]]s
  
[https://en.wikipedia.org/wiki/Phosphorus_sulfide Phosphorus sulfides] from many stable stiff highly cross-linked molecules. E.g.:
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== External links ==
* P<sub>4</sub>S<sub>10</sub> [https://en.wikipedia.org/wiki/Phosphorus_pentasulfide Phosphorus pentasulfide] – interrestingly this has diamondoid structure but it's limited to one molecule
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* P<sub>4</sub>S<sub>3</sub> [https://en.wikipedia.org/wiki/Phosphorus_sesquisulfide Phosphorus sesquisulfide]
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[https://en.wikipedia.org/wiki/Sulfur_nitride Sulfur nitrides] from many (somewhat) stable structures. E.g.:
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* [https://en.wikipedia.org/wiki/Inorganic_compound Inorganic compound] – the exact definition is field dependents, so taking a bit of liberty here should be ok.
* S<sub>4</sub>N<sub>4</sub> [https://en.wikipedia.org/wiki/Tetrasulfur_tetranitride Tetrasulfur_tetranitride] (shock sensitive)
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* (SN)<sub>x</sub> [https://en.wikipedia.org/wiki/Polythiazyl Polythiazyl]
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* (S)<sub>x</sub> Elemantal sulfur in form of long chains [https://en.wikipedia.org/wiki/Polysulfane polysulfane]s
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Latest revision as of 16:41, 1 July 2021

This article defines a novel term (that is hopefully sensibly chosen). The term is introduced to make a concept more concrete and understand its interrelationship with other topics related to atomically precise manufacturing. For details go to the page: Neologism.

Organic gemstones shall include all gemstones that ...

  • ... do not contain metals but only light non-metallic elements
  • ... do contain carbon

Organic gemstones typically ...

  • ... contain volatile elements (carbon, nitrogen)
  • ... are combustible.
  • ... become unstable if too much oxygen (or sulfur) is mechanosynthetically added

List of organic gemstone compounds (attempting exhaustiveness)

The options are rather limited so it seems here (for once) one quickly can arrive at a quite exhaustive list of the most basic possible structures.
As always on this wiki: The heavier more scarce elements (Arsenic, Selenium, ...) are excluded for materials for eventual large scale structural use.

  • C Diamond
  • C Lonsdaleite
  • β-C3N4 Beta carbon nitride – (possibly a fire hazard)
  • C?P? Likely some carbon phosphides (at least sheets) – eventual health hazard due to direct carbon phosphorus bonds (common in toxins)

Perhaps over(?)stretching it a bit:

And boron carbides like:


Why adding oxygen or sulfur only works for trace amounts

  • Adding oxygen in high quanity leads to carbon dioxide CO2 which is (as one should now) not stable as a covalently cross-linked solid
  • Adding sulfur in huge quantity leads to carbon disulfide CS2 wich is an (interesting) liquid in its thermodynamic stable form
  • Nitrogen just wants to mind it's own business and wants to get back to its molecular di-nitrogen from with its strong tripple bond (usually a quite exoergic reaction)

Metastable solid state forms (not referring to being frozen) may be possible (especially at low temperatures) but activation energies are low making these compounds into dangerous high energy explosives.

Related

External links

  • Inorganic compound – the exact definition is field dependents, so taking a bit of liberty here should be ok.