Difference between revisions of "Mechadensite"
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with extended unit cells of minimal size. | with extended unit cells of minimal size. | ||
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'''What is so special about this gemstone? …''' <br> | '''What is so special about this gemstone? …''' <br> | ||
Rutile TiO₂ is limited in hardness (Mohs 6 to 6.5) but thermally highly stable. <br> | Rutile TiO₂ is limited in hardness (Mohs 6 to 6.5) but thermally highly stable. <br> | ||
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'''A "mixing series" may allow for combining the advantages of both''' by <br> | '''A "mixing series" may allow for combining the advantages of both''' by <br> | ||
tuning the Si/Ti ratio such that the material attains both high mechanical and high thermal stability. | tuning the Si/Ti ratio such that the material attains both high mechanical and high thermal stability. | ||
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| + | == Related == | ||
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| + | * [[Pseudo phase diagram]] | ||
| + | * [[Titanium (chemical element)]] | ||
Revision as of 11:31, 10 June 2022
This is not an official name.
Allow me (author of this wiki) to be so vain as to name an unnatural and
not yet synthesizable gemstone with my main internet pseudonym.
Contents
Stoichometry and examples
The mechadensite series:
- General formula: SixTiyOz 2*(x+y)=z
Examples:
- SiTiO4 (equistoicometric mechadensite)
- Si3TiO8 (silicon leaning mechadensite – presumably more hardness and less thermal stability)
End members are:
- rutile TiO2 and
- stishovite SiO2 (isostructural to rutile thus not quartz).
Likely propertiers
- high hardness (Mohs 6 to Mohs 9)
- electrically non conductive wide band-gap
- optically transparent in visible spectral range
- strong optical dispersion
- high heat conductance (but far from diamond)
Not a solid solution mixing series
Regarding "mixing series" note that this is meant as a piezomechanosyntesized checkerboard compound.
It is not supposed to be a thermodynamic solid solution with statistically distributed (random) placement of atoms.
Such a solid solution might not even be accessible via thermodynamic production pathways,
that is melting mixing and recrystallizing.
It should be quite easy to figure out which Ti/Si ratios allow for symmetric checkerboard patterns
with extended unit cells of minimal size.
What is so special about this gemstone? …
Rutile TiO₂ is limited in hardness (Mohs 6 to 6.5) but thermally highly stable.
Stishovite SiO₂ is ultra hard (Mohs 8.5 to 9) but likely thermally less stable since
it's a metastable high pressure modification of quartz (SiO₂ too).
A "mixing series" may allow for combining the advantages of both by
tuning the Si/Ti ratio such that the material attains both high mechanical and high thermal stability.
