Difference between revisions of "S-block metals"
(→hard (silicates only?): refs to garnets grossular & pyrop) |
m (→barely soluble salts (*ates): refrepair) |
||
| Line 48: | Line 48: | ||
Other: | Other: | ||
| − | * '''K'''[AlSi<sub>3</sub>O<sub>8</sub>] orthoclase <ref>https://en.wikipedia.org/wiki/Orthoclase Wikipedia:Orthoclase</ref> Mohs 6 (defining mineral) and amazonite <ref>[https://de.wikipedia.org/wiki/Amazonit Wikipedia(de):Amazonit]</ref> Mohs 6-6.5 and sanidine (endmember?) <ref>[https://en.wikipedia.org/wiki/Sanidine Wikipedia:Sanidine]</ref> Mohs 6 | + | * '''K'''[AlSi<sub>3</sub>O<sub>8</sub>] orthoclase <ref>[https://en.wikipedia.org/wiki/Orthoclase Wikipedia:Orthoclase]</ref> Mohs 6 (defining mineral) and amazonite <ref>[https://de.wikipedia.org/wiki/Amazonit Wikipedia(de):Amazonit]</ref> Mohs 6-6.5 and sanidine (endmember?) <ref>[https://en.wikipedia.org/wiki/Sanidine Wikipedia:Sanidine]</ref> Mohs 6 |
* '''Na'''[AlSi<sub>3</sub>O<sub>8</sub>] albite (sodium placgioclase) <ref>[https://en.wikipedia.org/wiki/Albite Wikipedia:Albite]</ref> Mohs 6-6.5 | * '''Na'''[AlSi<sub>3</sub>O<sub>8</sub>] albite (sodium placgioclase) <ref>[https://en.wikipedia.org/wiki/Albite Wikipedia:Albite]</ref> Mohs 6-6.5 | ||
* '''Ca'''Al<sub>2</sub>Si<sub>2</sub>O<sub>8</sub> anorthite (calcium plagioclase) <ref>[https://en.wikipedia.org/wiki/Anorthite Wikipedia:Anthorite]</ref> Mohs 6 | * '''Ca'''Al<sub>2</sub>Si<sub>2</sub>O<sub>8</sub> anorthite (calcium plagioclase) <ref>[https://en.wikipedia.org/wiki/Anorthite Wikipedia:Anthorite]</ref> Mohs 6 | ||
Revision as of 18:48, 19 December 2015
Contents
s-block metals as material filler
The lighter ones of the alkali- and alkaline earth metals (the non-noble metals in the left s-block of the periodic table) belong to the most abundant elements around. Thus its an iteresting question wheter those elements can be combined with other abundant ones to make structural building materials.
solubility issue
The s-block metals need to be combined with other elements not only because metals are not very suitable for mechanosynthesis but also because they are extremely reactive in pure form. A self passivation oxide layer film like the one that macroscopic blocks of magnesium have is obviously not possible on nano sized building blocks. In contact to air oxidation would go down right to the core of the building block and blow up the part twice in volume destroying it completely.
Since s-block metals are so electropositive they tend to toss away their shell electron or pair of shell electrons and thus tend to form ionic salts. Such a salt usually has the form:
- positively charged s-block-metal + negatively charged nonmetal-acid
Polar salts of this form are easily dissolved in water since water is a polar solvent. But good water solubility is not what one usually wants from a typical building material - especially not if the solvent is toxic like it is the case with many beryllium compounds. So the focus here will be on the few non or barely water soluble compounds.
barely soluble salts (*ates)
soft
When systematically building combinations of s-block metals and d-block nonmetal acids one can find some barely soluble compounds:
- calcium carbonate CaCO3 (limestone/chalk ... calcite/aragonite/vaterite)
- calcium phosphates (similar to hydroxyapatit bone tooth-enamel)
- calcium silicate CaSiO3 (dry wall plates ... wollastonite)
- magnesium silicate Mg2SiO4 (forsterite - no crystal water - pretty hard - neosilicate - earth mantle mineral)
- magnesium silicate Mg3Si4O10(OH)2 (talc - a hydroxide - way too soft for a building material)
Beryllium silicates:
- beryl Be3Al2(SiO3)6 (cyclosilicate) wikipedia
varieties: emerald (green Cr), aquamarine (blue Fe), red beryl (red Mn), goshenite (colorless), heliodor (yellow Fe), and morganite (pink Mn) - phenakite Be2SiO4 (neosilicate)
- bertrandite Be4Si2O7(OH)2 (hydorxide - pretty hard - sorosilicate)
hard (silicates only?)
Some harder silicate compounds containing aluminum too are:
- LiAl(SiO3)2 spodumene [1] Mohs 6.5-7 (contains unabundant lithium)
- KAlSi2O6 leucite [2] Mohs 5.5-6
- NaAlSi2O6 jadeite (a chain/band silicate) [3] Mohs 6.5-7
- Ca3Al2(SiO4)3 grossularite [4] Mohs 7-7.5 (an ugrandite garnet and nesosilicate)
- Mg3Al2(SiO4)3 pyrope [5] Mohs 7-7.5 (a pyralspite garnet and nesosilicate)
Ugrandite garnets (hard) are defined by their calcium content:
- grossularite Ca3Al2(SiO4)3
- andradite Ca3Fe2(SiO4)3
- uwarovite Ca3Cr2(SiO4)3 (contains unabundant chromium)
Other:
- K[AlSi3O8] orthoclase [6] Mohs 6 (defining mineral) and amazonite [7] Mohs 6-6.5 and sanidine (endmember?) [8] Mohs 6
- Na[AlSi3O8] albite (sodium placgioclase) [9] Mohs 6-6.5
- CaAl2Si2O8 anorthite (calcium plagioclase) [10] Mohs 6
- MgAl2Si2O8 magnesium aluminosilicate (there are various associated hydroxide minerals => solubility?)
non salts but (*ides)
Probably the simplest barely soluble earth alkali compounds (that are not salts) are:
- MgO (periclase ... magnesia) magnesium oxide (nontoxic)
- CaF2 (fluorite) calcium fluoride
- BeO (brommelite Mohs 9) [11] beryllium oxide
- BeAl2O4 chrysoberyl
[todo:]
- [find some insoluble alkali compounds Li Na K]
- [maybe find some compounds of the heavier and less abundant ones (Rb & Cs) (Sr & Ba)]
- [treat aluminum as special case]
