Ligand field theory

d-orbitals and f-orbitals as they fall out of the math of the Schrödinger equation are not in match with the real situation. Other methods like crystal field theory and ligand field theory are used instead.

How it works

(wiki-TODO: Add a ultra-brief up-to speed explanation of ligand field theory)

Related

• Atomic orbitals
• Fun with spins
• Electronic transitions – Inter system crossing

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• Optical effects – see "photonic steampunk" section
• Color emulation – Passive color gemstone display – Active color gemstone display

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See: Organometallic gemstone-like compound – Tuning gemstone color:

• either ultra precisely with Kaehler brackets
• or with fast programmable active pressure adjusting actuation