White sapphire

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Advantages:

  • very hard material, very high heat conductivity
  • made out of the extremely common element aluminum (more common than carbon)
  • thermodynamically stable not just metastable thus very heat resistant

Disadvantage:
Crystal structure of less high symmetry than other interesting base materials.
Maybe look at metastable polymorphs at the eventual cost of somewhat less heat resistance?

Note: The page uses leukosapphire instead of just sapphire because
just sapphire is often associated with a blue to black variant where the colour is caused by metal impurities.
A base material for gemstone metamaterial technology would be perfectly impurity free and colorless clear though.
Like a leukosapphire just better.

Related

External links

  • materialsproject.org [1]
  • mineralienatlas (de) [2]
  • Strukturtypendatenbank uni-freiburg: [3]