Difference between revisions of "Carbon"
From apm
(initial version - so so) |
(→Related: added links to other elements in the same group ti the == Related == section) |
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* [[Diamondoid]] | * [[Diamondoid]] | ||
* [[Diamond]] | * [[Diamond]] | ||
+ | * Elements in the same group: '''Carbon''', [[Silicon]], [[Germanium]], [[Tin]], [[Lead]] | ||
== External links == | == External links == |
Revision as of 17:29, 21 June 2020
See: Gemstone like compound#Carbons versatility
sp3 allotropes:
- Diamond (cubic)
- Lonstaleite (hexagonal)
- ...
sp2 allotropes:
- Buckyballs (convex curvature; concave from inside) – weak molecular solids
- Nanotubes (no curvature – flat rolled)
- 3D meshes (hyperbolic curvature)
- "penta graphene" (cairo pattern)
- ...
Binary compounds:
- Silicon carbide SiC aka moissanite
- carbon nitrides: beta carbon nitride and cubic gauche carbon nitride
- Titanium carbide TiC aka titanium-khamrabaevite (cubic rock salt structure) Mohs 9-9.5 refractory
- Vanadium carbide VC (vanadium is not too common) vanadium-khamrabaevite
similar is: NbC and TaC (Nb is not abundant, Ta is extremely rare) - Zirconium cabide ZrC [1] (same structure but no natural mineral present)
similar is: HfC (Hf is pretty rare) - Iron carbide (this here is not cementite!!) iron-khamrabaevite (unknown stability, likely very hard)
- Chromium_carbide (various stoichiometric & structures - may point to useful covalent behavior)
Cr3C2 Tongbaite (refractory, Mohs 9.6; orthorhombic; 6.64g/ccm) Cr is not too abundant - Molybdenium carbide (de) Mo2C (insoluble, two modifications α and β) Mo is rather rare
- Tungsten_carbide (hexagonal, Mohs 9) W is rather rare
- Fe3C, Ni3C, Co3C cohenite endmembers (likely rather metallic, Mohs 5.5-6)
- copper and zinc are more electronegative => more covalent behavior => organometallic compounds
- Boron carbide B4C [2] (boron is not too common)
- Aluminium carbide [3] (reacts with water - releases methane gas CH4)
- Beryllium carbide Be2C (very hard but reactive, toxic and rare)
- Magnesium carbide ???
- Calcium carbide CaC2 (an acetylide - reacts with water - releases ethyne gas C2H2)
- TODO: La, Ce, (Li, Na, K)
Related
External links
- Wikipedia: Pi bond
- Wikipedia: Orbital hybridisation
- Wikipedia: Carbides and Category:Carbides
- Wikipedia: Graphite_intercalation_compound KC8
- Wikipedia: Metal_carbido_complex (Transition metal carbides)
- Wikipedia: Metallocarbohedryne