View source for List of proposed tooltips for diamond mechanosynthesis

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From the paper: <br>
"A Minimal Toolset for Positional Diamond Mechanosynthesis" <br>
See: [[Tooltip chemistry]]

= Tools =

== (A) HAbst tool ==

* '''R<sub>3</sub>C-C≡C·'''
* R<sub>3</sub>C-C≡C-H ("discharged")

== (B) HDon tool ==

* '''R<sub>3</sub>Ge-H'''
* R<sub>3</sub>Ge· ("discharged" it becomes the GeRad handle)

== (C) HTrans tool ==

* '''R<sub>3</sub>C-C≡(C-H)-GeR<sub>3</sub>'''

== (D) DimerP tool ==

* '''R<sub>3</sub>Ge-C≡C-GeR<sub>3</sub>'''
* '''R<sub>3</sub>Ge· ·GeR<sub>3</sub>''' (the R's are connected in a close stiff loop the background)

== (E) AdamRad handle ==

* '''R<sub>3</sub>C·'''

== (F) GeRad handle ==

* '''R<sub>3</sub>Ge·'''

== (G) Methylene tool ==

* '''R<sub>3</sub>C-CH<sub>2</sub>'''

== (H) Germylmethylene tool ==

* '''R<sub>3</sub>Ge-CH<sub>2</sub>'''

== (I) Germylene tool ==

* '''R<sub>3</sub>C-GeH<sub>2</sub>'''

= Reactions Sequences (RSx) =

== RS1 – hydrogen abstractions ==

== RS2 – hydrogen donation ==

== RS3 – hydrogen donation with the HTrans tool ==

== RS4 Dimer placement ==

== RS5 hydrogen recharge step ==

Moving a hydrogen:
* from a saturated HAbst tool 
* to a depleted HDon tool (a GeRad handle)
* by means of another "catalyzing" GeRad handle

== RS6 recharge DimerP ==

Using HTrans tool and GeRad tool to <br>
recharge DimperP tool leaving <br>
Two GeRad and one Adamrad handles.

== RS7 carbon deposition (adam sidewall) ==

"Add 1st CH<sub>3</sub> to Adam sidewall using GM tool."

== RS8 carbon deposition (sidewall) ==

"Add 1st CH<sub>3</sub> to Adam sidewall using Meth tool."

== RS9 carbon deposition (adam bridgehead) ==

"Add 1st CH<sub>3</sub> to Adam bridgehead using GM tool."

== RS10 carbon deposition (adam bridgehead) ==

"Add 1st CH<sub>3</sub> to Adam bridgehead using Meth tool."

== RS11 carbon deposition (adam bridgehead) ==

"Add 1st CH<sub>3</sub> to Adam bridgehead using Meth tool."

== RS12 carbon deposition (C111 bridgehead) ==

"Add 1st CH<sub>3</sub> to C111 bridgehead using GM tool."

== RS13 carbon deposition (C110 ridge site) ==

"Add 1st CH3to C110 ridge site using GM tool."

== RS14 carbon deposition (C100 dimer site) ==

"Add 1st CH3to C100 dimer site using GM tool."

== MANY MORE REACTION SEQUENCES ... ==

== R37 (gas phase step)==

"Build HAbst tool by pulling bound C2H2off of a Ge surface"

== R38 recharging DimerP with HAbst (leaving AdamRad) ==

== R40 (gas phase step) ==

== RS42 (gas phase step) ==

== RS59 (gas phase step) ==

== RS65 ==

(last sequence of the paper)

= Related =

* [[Tooltip chemistry]]
* [[Tooltip cycle]]
* [[A Minimal Toolset for Positional Diamond Mechanosynthesis (paper)]]
* [[Piezochemical mechanosynthesis]]
* [[Resource molecules]]