Titanosapphire

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Stoichometric checkerboard compounds between the isostructural gemstones of
leukosapphire and tistarite (these share the hematite structure)

Hematite can be a third end-member.
It is mechanically weaker but brings conductivity.
Possibly making for a tunable semiconcuctor.

See: Simple crystal structures of especial interest

Related pages

Other neo-polymorphs: