Tether assisted self assembly: Difference between revisions
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m added link to unwritten page sequential flush-by washout self-assembly |
m added headlines |
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* quicker rates of selfassembly | * quicker rates of selfassembly | ||
* more site selective self-assembly | * more site selective self-assembly | ||
== quicker == | |||
Just as in [[self folding]] enforced local proximity leading to <br> | Just as in [[self folding]] enforced local proximity leading to <br> | ||
higher local [[effective concentration]] and thus to higher reaction rates. <br> | higher local [[effective concentration]] and thus to higher reaction rates. <br> | ||
== more selective == | |||
With some tricks (protection & deprotection, avoiding [[one-pot self-assembly]] going for [[sequential flush-by washout self-assembly]], …) <br> | With some tricks (protection & deprotection, avoiding [[one-pot self-assembly]] going for [[sequential flush-by washout self-assembly]], …) <br> | ||
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[[tether assisted positional assembly]] ([[mechanosynelf assembly]]) <br> | [[tether assisted positional assembly]] ([[mechanosynelf assembly]]) <br> | ||
= Related = | |||
* [[Tether assisted assembly]] | * [[Tether assisted assembly]] | ||
Revision as of 08:45, 30 April 2026
The idea is basically self folding but guiding larger beads on a string for:
- quicker rates of selfassembly
- more site selective self-assembly
quicker
Just as in self folding enforced local proximity leading to
higher local effective concentration and thus to higher reaction rates.
more selective
With some tricks (protection & deprotection, avoiding one-pot self-assembly going for sequential flush-by washout self-assembly, …)
it may be also usable to constrain the binding space much like in the case of
tether assisted positional assembly (mechanosynelf assembly)