Zincblende structure - Revision history

Apm: removed again - wrong page

2021-04-25T09:32:23Z

removed again - wrong page

← Older revision		Revision as of 11:32, 25 April 2021
Line 67:		Line 67:
	= External links =		= External links =

	~~Wikipedia:~~		* ...
	* ~~[https://en~~.~~wikipedia~~.~~org/wiki/Strukturbericht_designation Strukturbericht_designation]~~

Apm: added link to wikipedia page: Strukturbericht_designation

2021-04-25T09:31:47Z

added link to wikipedia page: Strukturbericht_designation

← Older revision		Revision as of 11:31, 25 April 2021
Line 64:		Line 64:
	* [[Wurtzite structure]] - layers ABAB		* [[Wurtzite structure]] - layers ABAB
	* Zincblende structure - layers ABCABC		* Zincblende structure - layers ABCABC

			= External links =

			Wikipedia:
			* [https://en.wikipedia.org/wiki/Strukturbericht_designation Strukturbericht_designation]

Apm: /* Pseudo phase diagrams surrounding ZnS */ added link to yet unwritten page cinnabar structure

2021-04-25T09:30:20Z

Pseudo phase diagrams surrounding ZnS: added link to yet unwritten page cinnabar structure

← Older revision		Revision as of 11:30, 25 April 2021
Line 31:		Line 31:
	Below Zinc there is cadmium and mercury both rare and toxic. <br>		Below Zinc there is cadmium and mercury both rare and toxic. <br>
	* CdS [https://en.wikipedia.org/wiki/Cadmium_sulfide cadmium_sulfide] has zinkblende structure => all [[psuedo polymorphs]] possible		* CdS [https://en.wikipedia.org/wiki/Cadmium_sulfide cadmium_sulfide] has zinkblende structure => all [[psuedo polymorphs]] possible
	* α-HgS [https://en.wikipedia.org/wiki/Cinnabar cinnabarite] wants to be trigonal rather than cubic		* α-HgS [https://en.wikipedia.org/wiki/Cinnabar cinnabarite] wants to be trigonal rather than cubic - [[cinnabar structure]]

	== Rift between pseudo phase diagrams ==		== Rift between pseudo phase diagrams ==

Apm: added note on natural moissanites more complex A,B,C stack

2021-04-25T07:03:13Z

added note on natural moissanites more complex A,B,C stack

← Older revision		Revision as of 09:03, 25 April 2021
Line 1:		Line 1:
	{{Stub}} __NOTOC__		{{Stub}} __NOTOC__

	* '''SiC''' [[moissanite]]		* '''SiC''' cubic [[moissanite]] - Note: natural moissanite is neither cubic nor hexagonal. It's a more complex stacks of A,B,C layers.
	-----		-----
	* '''C''' [[diamond]]		* '''C''' [[diamond]]

Apm: /* Related */ spelling

2021-04-25T06:59:45Z

Related: spelling

← Older revision		Revision as of 08:59, 25 April 2021
Line 63:		Line 63:
	* [[Simple crystal structures of especial interest]]		* [[Simple crystal structures of especial interest]]
	* [[Wurtzite structure]] - layers ABAB		* [[Wurtzite structure]] - layers ABAB
	* ~~Zinclblende~~ structure - layers ABCABC		* Zincblende structure - layers ABCABC

Apm: /* Related */ added link to Wurtzite structure

2021-04-25T06:59:31Z

Related: added link to Wurtzite structure

← Older revision		Revision as of 08:59, 25 April 2021
Line 62:		Line 62:

	* [[Simple crystal structures of especial interest]]		* [[Simple crystal structures of especial interest]]
			* [[Wurtzite structure]] - layers ABAB
			* Zinclblende structure - layers ABCABC

Apm: /* Misc */ added note on strong nonmetallicness despite high metal content

2021-04-24T12:57:24Z

Misc: added note on strong nonmetallicness despite high metal content

← Older revision		Revision as of 14:57, 24 April 2021
Line 46:		Line 46:
	= Misc =		= Misc =

	Also a very simple but different ([[oddball compounds\|odd]]) cubic structure: Cu<sub>2</sub>O cuprite.		* Also a very simple but different ([[oddball compounds\|odd]]) cubic structure: Cu<sub>2</sub>O cuprite.
			* Silver Ag (below Cu) does the same - Ag<sub>2</sub>O [https://en.wikipedia.org/wiki/Silver_oxide silver_oxide] (no mineral it seems)

			Nonmetallicness despite high metal content:

			Covalent behavior and nonmetallic optical and electrical behavious may have to do with <br>
			noble metals on the right having almost full electron shells and all electrons being used for covalent bonds no electrons left for semi-conductive or conductive behavior. <br>
			All that despite these compounds are 2/3 metal 1/3 oxygen.

			* ZnO<sub>2</sub> ?? ...

			* Complement to that ...

	= Related =		= Related =

	* [[Simple crystal structures of especial interest]]		* [[Simple crystal structures of especial interest]]

Apm: put stuff in the right chapter, swapped chapters, added a bit

2021-04-24T12:46:14Z

put stuff in the right chapter, swapped chapters, added a bit

← Older revision		Revision as of 14:46, 24 April 2021
Line 20:		Line 20:
	Like e.g. Lead carbide (combining the biggest and smallest atoms of the group) is not achievable via thermodynamic means. <br>		Like e.g. Lead carbide (combining the biggest and smallest atoms of the group) is not achievable via thermodynamic means. <br>
	And it's unclear if even via [[mechanosynthesis\|mechanosynthetic]] means.		And it's unclear if even via [[mechanosynthesis\|mechanosynthetic]] means.

	~~== Rift between pseudo phase diagrams ==~~

	~~SiC and ZnS have the same structure but there seems to be an unbridgable rift for [[pseudo phase diagram]]s. <br>~~
	~~With other nonmetals sulfur usually assumes bond order two (like oxygen above) but in ZnS it assumes bond order four.~~

	== Pseudo phase diagrams surrounding ZnS ==		== Pseudo phase diagrams surrounding ZnS ==

	Investigating the [[pseudo phase diagram]]s that emanate from ZnS		Investigating the [[pseudo phase diagram]]s that emanate from ZnS

	* CS<sub>2</sub> is an ([[oddball compound\|odd]]) liquid.
	* SiS<sub>2</sub> is an ([[oddball compound\|odd]]) polymeric compound.
	* Zinc carbide ???
	* Zinc silicide ???

	'''Replacing sulfur:''' <br>		'''Replacing sulfur:''' <br>
Line 42:		Line 32:
	* CdS [https://en.wikipedia.org/wiki/Cadmium_sulfide cadmium_sulfide] has zinkblende structure => all [[psuedo polymorphs]] possible		* CdS [https://en.wikipedia.org/wiki/Cadmium_sulfide cadmium_sulfide] has zinkblende structure => all [[psuedo polymorphs]] possible
	* α-HgS [https://en.wikipedia.org/wiki/Cinnabar cinnabarite] wants to be trigonal rather than cubic		* α-HgS [https://en.wikipedia.org/wiki/Cinnabar cinnabarite] wants to be trigonal rather than cubic

			== Rift between pseudo phase diagrams ==

			SiC and ZnS have the same structure but there seems to be an unbridgable rift for [[pseudo phase diagram]]s. <br>
			With other nonmetals sulfur usually assumes bond order two (like oxygen above) but in ZnS it assumes bond order four.

			Cross combining the elements leads to some odd compounds instead of a preserved structure. See:
			* CS<sub>2</sub> is an ([[oddball compound\|odd]]) liquid.
			* SiS<sub>2</sub> is an ([[oddball compound\|odd]]) polymeric compound.
			* Zinc carbide ??? barely any info
			* Zinc silicide ??? barely any info

	= Misc =		= Misc =

Apm: /* Pseudo phase diagrams surrounding SiC */ link fix

2021-04-24T12:41:13Z

Pseudo phase diagrams surrounding SiC: link fix

← Older revision		Revision as of 14:41, 24 April 2021
Line 19:		Line 19:
	The heavier ones likely only within bounds. <br>		The heavier ones likely only within bounds. <br>
	Like e.g. Lead carbide (combining the biggest and smallest atoms of the group) is not achievable via thermodynamic means. <br>		Like e.g. Lead carbide (combining the biggest and smallest atoms of the group) is not achievable via thermodynamic means. <br>
	And it's unclear if even via [mechanosynthesis\|mechanosynthetic]] means.		And it's unclear if even via [[mechanosynthesis\|mechanosynthetic]] means.

	== Rift between pseudo phase diagrams ==		== Rift between pseudo phase diagrams ==

Apm: /* Pseudo phase diagrams surrounding SiC */

2021-04-24T12:40:54Z

Pseudo phase diagrams surrounding SiC

← Older revision		Revision as of 14:40, 24 April 2021
Line 18:		Line 18:
	All the carbon group elmenets can be substitutes. <br>		All the carbon group elmenets can be substitutes. <br>
	The heavier ones likely only within bounds. <br>		The heavier ones likely only within bounds. <br>
	Like e.g. Lead carbide (biggest and smallest atoms of the group) is not achievable via thermodynamic means. <br>		Like e.g. Lead carbide (combining the biggest and smallest atoms of the group) is not achievable via thermodynamic means. <br>
	And it's unclear if even via [mechanosynthesis\|mechanosynthetic]] means.		And it's unclear if even via [mechanosynthesis\|mechanosynthetic]] means.