Machine-phase chemistry - Revision history

Apm: added headline and link to page the finger problems

2023-06-08T13:51:11Z

added headline and link to page the finger problems

← Older revision		Revision as of 15:51, 8 June 2023
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	* can largely increase rates for the actually desired reaction (higher [[effective concentration]])		* can largely increase rates for the actually desired reaction (higher [[effective concentration]])

	Generally this guiding …		Strongly related to machine-phase chemistry are [[the finger problems]].

			== Keeping up total reaction rate - spacetime reaction density ==

			Generally this positional guiding of reactants …
	* reduces the spacial density (spacial frequency) of active reaction sites		* reduces the spacial density (spacial frequency) of active reaction sites
	* increases the temporal frequency (temporal density) of reaction events		* increases the temporal frequency (temporal density) of reaction events

Apm: /* Absence of endoergic reactions */ linebreaks

2023-06-08T13:48:06Z

Absence of endoergic reactions: linebreaks

← Older revision		Revision as of 15:48, 8 June 2023
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	Endoergic reactions progress forward because they dump more entropy into position space than what they suck out of impulse space. <br>		Endoergic reactions progress forward because they dump more entropy into position space than what they suck out of impulse space. <br>
	As machine phase has per definition an entropy of zero in position space that is never growing ~~alwas~~ instantly reset within each assembly step by pumping entropy out to impulse space (heat) endoergic reactions are impossible in machine phase.		As machine phase has per definition an entropy of zero in position space that is <br>
			never growing (always instantly reset within each assembly step by pumping entropy out to impulse space (heat)) <br>
			'''endoergic reactions are impossible in machine phase'''.

	Well, excluding things that are within machine phase safely encapsulated and have an interior that is intentionally not in machine phase. <br>		Well, excluding things that are within machine phase safely encapsulated and have an interior that is intentionally not in machine phase. <br>

Apm: /* Pseudoendoergic ripp-off reactions */ chemomechanical conversion

2023-06-08T13:46:25Z

Pseudoendoergic ripp-off reactions: chemomechanical conversion

← Older revision		Revision as of 15:46, 8 June 2023
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	Still reactions that need energy for bond splitting can be performed by applying force <br>		Still reactions that need energy for bond splitting can be performed by applying force <br>
	~~basically~~ stiffly linking the reaction to an other reaction located elsewhere that is <br>		Basically this is done by stiffly linking the reaction to an other reaction located elsewhere that is <br>
	more exoergic than what the splitting process needs. See: [[exoergicity offloading]] <br>		more exoergic than what the splitting process needs. A site for [[chemomechanical conversion]]. See: [[exoergicity offloading]] <br>
	Related: [[Lagrangian mechanics for nanomechanical circuits]] and [[Drive subsystem of a gem-gum factory]]		Related: [[Lagrangian mechanics for nanomechanical circuits]] and [[Drive subsystem of a gem-gum factory]]

Apm: a lot of extenssions

2023-06-08T13:43:33Z

a lot of extenssions

@@ Line 10: / Line 10: @@
 The latter must and can overcompensate in for the loss in the former.
-Actively applying force can accelerate reactions further in some cases. <br>
+== Applying forces ==
 In some cases applied force can slow down reactions though. See: [[Inter system crossing]]. <br>
 Higly exoergic >>kT reactions with no energy recuperation will typically happen fast. <br>
-Energy recuperation (and maybe even [[dissipation sharing]] to squeez out as much efficiency as possible) <br>
+Energy recuperation (and maybe even [[dissipation sharing]] to squeeze out as much efficiency as possible) <br>
-will change reaction range rates in nontrivial ways.
+will change reaction range rates in nontrivial ways. Related: [[Energy recuperation]] & [[Reversible actuation]]
 == Related ==

Apm: added links to 4 related pages

2023-06-08T13:25:43Z

added links to 4 related pages

← Older revision		Revision as of 15:25, 8 June 2023
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	----		----
	* [[Tooltip chemistry]] (not necessarily force applying)		* [[Tooltip chemistry]] (not necessarily force applying)
	* [[Piezomechanochemistry]] (not [[Piezochemistry]])		* [[Piezomechanochemistry]] (not [[Piezochemistry]]!!) with the two cases of: <br>[[Piezochemical mechanosynthesis]] and [[Chemomechanical converter]]s
	* [[Chemomechanical converter]]
	----		----
	* [[Mechanosynthesis core]]		* [[Mechanosynthesis core]]
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	----		----
	* [[Tooltip cycle]]		* [[Tooltip cycle]]
			* [[A Minimal Toolset for Positional Diamond Mechanosynthesis (paper)]]
			* [[List of proposed tooltips for diamond mechanosynthesis]]
	----		----
			* [[Resource molecules]]
	* [[Positional assembly]]		* [[Positional assembly]]

Apm: basic page

2023-06-08T13:21:17Z

basic page

New page

{{stub}}

Guiding reactive [[moieties]] along tightly controlled paths …
* can largely suppress unwanted side reactions
* can largely increase rates for the actually desired reaction (higher [[effective concentration]])

Generally this guiding …
* reduces the spacial density (spacial frequency) of active reaction sites
* increases the temporal frequency (temporal density) of reaction events
The latter must and can overcompensate in for the loss in the former.

Actively applying force can accelerate reactions further in some cases. <br>
In some cases applied force can slow down reactions though. See: [[Inter system crossing]]. <br>
Higly exoergic >>kT reactions with no energy recuperation will typically happen fast. <br>
Energy recuperation (and maybe even [[dissipation sharing]] to squeez out as much efficiency as possible) <br>
will change reaction range rates in nontrivial ways.

== Related ==

* '''[[Effective concentration]]'''
* '''[[Machine phase]]'''
----
* [[Tooltip chemistry]] (not necessarily force applying)
* [[Piezomechanochemistry]] (not [[Piezochemistry]])
* [[Chemomechanical converter]]
----
* [[Mechanosynthesis core]]
* [[Molecular mill]]
----
* [[Tooltip cycle]]
----
* [[Positional assembly]]