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	<id>https://apm.bplaced.net/w/index.php?action=history&amp;feed=atom&amp;title=Implosion_nanofabrication</id>
	<title>Implosion nanofabrication - Revision history</title>
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	<updated>2026-04-20T14:54:59Z</updated>
	<subtitle>Revision history for this page on the wiki</subtitle>
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		<id>https://apm.bplaced.net/w/index.php?title=Implosion_nanofabrication&amp;diff=12782&amp;oldid=prev</id>
		<title>Apm: basic page</title>
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		<updated>2022-07-02T08:13:18Z</updated>

		<summary type="html">&lt;p&gt;basic page&lt;/p&gt;
&lt;p&gt;&lt;b&gt;New page&lt;/b&gt;&lt;/p&gt;&lt;div&gt;&lt;br /&gt;
Implosion fabrication is a manufacturing method that allows for very small &amp;lt;br&amp;gt;&lt;br /&gt;
(but not yet atomically precise) electric leads down to the low single digit nanometer scale &amp;lt;br&amp;gt;&lt;br /&gt;
without the need for hard to access and/or very expensive silicon chip production lab.&lt;br /&gt;
&lt;br /&gt;
While there are processes for making such small leads on silicon these are at the cutting edge (2022) and only accessible &amp;lt;br&amp;gt;&lt;br /&gt;
for one-off masks for processors produced in high quantities and very expensive. &amp;lt;br&amp;gt;&lt;br /&gt;
More accessible fabrication labs are still expensive (how expensive?) and much lower resolution.&lt;br /&gt;
&lt;br /&gt;
== Detailed summary ==&lt;br /&gt;
&lt;br /&gt;
Below is a bullet-pointed summary from the paper: &amp;lt;br&amp;gt;&lt;br /&gt;
&amp;quot;3D nanofabrication by volumetric deposition and controlled shrinkage of patterned scaffolds&amp;quot; &amp;lt;br&amp;gt;&lt;br /&gt;
http://science.sciencemag.org/content/362/6420/1281&lt;br /&gt;
&lt;br /&gt;
&amp;#039;&amp;#039;&amp;#039;Process:&amp;#039;&amp;#039;&amp;#039;&lt;br /&gt;
* starting out with acrylate hydrogel base (x10 or x20 cross-linked)&lt;br /&gt;
* infusion with functionalized fluorescin&lt;br /&gt;
* two photon excitation links fluorescin to hydrogel (at a second site beside the functionalised one)&lt;br /&gt;
* &amp;quot;patterning&amp;quot;: the functionalized fluorescing is linked voxel by voxel (via reverse operated optical microscope?) &amp;lt;br&amp;gt;(quite strong) anisotropic distortion can be accounted for (it&amp;#039;s repeatable)&lt;br /&gt;
* &amp;quot;removal&amp;quot;: remaining fluorescin is washed out&lt;br /&gt;
* repetition with differently functionalized fluorescin is possible, but contamination of the former one about 20%&lt;br /&gt;
* depositing materials on the patterned active groups (via conjugation chemistries)&lt;br /&gt;
* &amp;quot;intensification&amp;quot;: depositing more where there already is some of the same&lt;br /&gt;
* (in case of metals like silver: chelate excess metal to suppress conductivity at undesired places)&lt;br /&gt;
* &amp;quot;shrinking&amp;quot;: contracting hydrogel by adding hydrochloric acid or MgCl2 (only former allows next step)&lt;br /&gt;
* &amp;quot;shrinking further&amp;quot;: by dehydration&lt;br /&gt;
* in case of metals like silver: &amp;quot;sintering&amp;quot;: by repeating the optical patterning in case of deposited silver&lt;br /&gt;
&lt;br /&gt;
&amp;#039;&amp;#039;&amp;#039;Limits:&amp;#039;&amp;#039;&amp;#039;&lt;br /&gt;
* not atomically precise (surface roughness comes near, but no control over individual atoms)&lt;br /&gt;
* not atomically accurate&lt;br /&gt;
* no hollow voids, scaffold remains in final product&lt;br /&gt;
* product not resilient to water&lt;br /&gt;
* still relatively experimental ([[technology readiness level]]?)&lt;br /&gt;
&lt;br /&gt;
&amp;#039;&amp;#039;&amp;#039;Capabilities:&amp;#039;&amp;#039;&amp;#039;&lt;br /&gt;
* shrunken voxels ~50nm&lt;br /&gt;
* discontinuous conductors with high conductivity&lt;br /&gt;
* no overhang limitations (no layer by layer deposition involved, layer by layer exposure possible)&lt;br /&gt;
* Many materials possible: metals, semiconductors, and biomolecules&lt;br /&gt;
* in particular: highly conductive, 3D silver nanostructures within an acrylic scaffold (the dried hydrogel)&lt;br /&gt;
* big maximal build volume (what exactly effectively after full shrinking?)&lt;br /&gt;
* already very fast and can be made even faster&lt;br /&gt;
&lt;br /&gt;
== Related ==&lt;br /&gt;
&lt;br /&gt;
&lt;br /&gt;
* [[Non atomically precise nanomanufacturing methods]]&lt;br /&gt;
* [[MEMS]]&lt;/div&gt;</summary>
		<author><name>Apm</name></author>
	</entry>
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