Highly polycyclic small molecule - Revision history

Apm: Category:Incremental path Category:Direct path

2026-03-29T19:01:26Z

Category:Incremental path Category:Direct path

← Older revision		Revision as of 21:01, 29 March 2026
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	* [https://en.wikipedia.org/wiki/Azaborane Azaborane]		* [https://en.wikipedia.org/wiki/Azaborane Azaborane]
	* [https://en.wikipedia.org/wiki/Carborane Carboranes]		* [https://en.wikipedia.org/wiki/Carborane Carboranes]

			[[Category:Incremental path]]
			[[Category:Direct path]]

Apm: shifting headlines & some refinement

2022-05-30T11:40:06Z

shifting headlines & some refinement

← Older revision		Revision as of 13:40, 30 May 2022
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	Some of these even do conformational changes on optical activation. <br>		Some of these even do conformational changes on optical activation. <br>
	So these could, beside their stiffness provide the functionality of optically activated nanoscale actuators.		So these could, beside their stiffness provide the functionality of optically activated nanoscale actuators.

	~~== Misc ==~~

	=== Boron clusters ===		=== Boron clusters ===
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	Some mostly structure preserving substitutions are often possible with e.g. carbon or nitrogen.		Some mostly structure preserving substitutions are often possible with e.g. carbon or nitrogen.

	=== ~~Polyoxymetallates~~ ===		=== Polyoxymetallate clusters ===

	Polyoxymetallates (e.g. molybdenum oxides) can form ~~atomically precise~~ nano-clusters ~~which~~ can be considered big molecules.		Polyoxymetallates (e.g. molybdenum oxides) can form nano-clusters that terminate in their selfassembly
			reaching atomically precise structures. These can be considered big atomically precise molecules.

	=== Metalorganic structures (terminating in selfassembly) ===		=== Metalorganic structures (terminating in selfassembly) ===
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	Various options for how many chelating molecules clasp how many metal ions. <br>		Various options for how many chelating molecules clasp how many metal ions. <br>
	Metalorgainic bonds may me more or less covalent in character.		Metalorgainic bonds may me more or less covalent in character.

			== Misc ==

	=== 2D aromatic molecules & (mechano)optical activity ===		=== 2D aromatic molecules & (mechano)optical activity ===

Apm: /* Misc */ added note on boron clusters, polyoxymetallates, metalorganic structures

2022-05-30T11:37:29Z

Misc: added note on boron clusters, polyoxymetallates, metalorganic structures

@@ Line 50: / Line 50: @@
 == Misc ==
-Aromatic polycyclic compounds are also often optically active <br>
+=== Boron clusters ===
-and potentially of interest as basis for [[optically activated nanoscale actuators]].
 == Related ==

Apm: /* External links */

2022-05-18T17:21:27Z

External links

← Older revision		Revision as of 19:21, 18 May 2022
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	=== Adamantane related work ===		=== Adamantane related work ===

	'''Awesome graphics''' thereto (and coupling to nanotubes) on		'''Awesome graphics''' thereto (and coupling to nanotubes)
	[https://www.somewhereville.com/the-design-of-carbon-nanotube-based-dative-structures-from-supramolecular-principles/ www.somewhereville.com]<br>		[https://www.somewhereville.com/the-design-of-carbon-nanotube-based-dative-structures-from-supramolecular-principles/ on www.somewhereville.com]<br>
	In peculiar this slide: [https://www.somewhereville.com/rescv/foresight_2002/foresight200207.jpg Dative-Based Molecular Building Blocks – Graphic by Damian G. Allis – Idea by Ralph C. Merkle (2000)]		In peculiar this slide: [https://www.somewhereville.com/rescv/foresight_2002/foresight200207.jpg Dative-Based Molecular Building Blocks – Graphic by Damian G. Allis – Idea by Ralph C. Merkle (2000)]

Apm: /* External links */ added direct link to slide

2022-05-18T17:20:56Z

External links: added direct link to slide

← Older revision		Revision as of 19:20, 18 May 2022
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	'''Awesome graphics''' thereto (and coupling to nanotubes) on		'''Awesome graphics''' thereto (and coupling to nanotubes) on
	[https://www.somewhereville.com/the-design-of-carbon-nanotube-based-dative-structures-from-supramolecular-principles/ www.somewhereville.com]		[https://www.somewhereville.com/the-design-of-carbon-nanotube-based-dative-structures-from-supramolecular-principles/ www.somewhereville.com]<br>
			In peculiar this slide: [https://www.somewhereville.com/rescv/foresight_2002/foresight200207.jpg Dative-Based Molecular Building Blocks – Graphic by Damian G. Allis – Idea by Ralph C. Merkle (2000)]

	* 2020 Complexes Between Adamantane Analogues B4X6 -X = {CH2, NH, O ; SiH2, PH, S} - and Dihydrogen, B4X6:nH2 (n = 1–4)<br>[https://www.mdpi.com/1420-3049/25/5/1042/htm at www.mdpi.com]		* 2020 Complexes Between Adamantane Analogues B4X6 -X = {CH2, NH, O ; SiH2, PH, S} - and Dihydrogen, B4X6:nH2 (n = 1–4)<br>[https://www.mdpi.com/1420-3049/25/5/1042/htm at www.mdpi.com]

Apm: /* Adamantane related building blocks */ added systematic names

2022-05-18T17:15:24Z

Adamantane related building blocks: added systematic names

← Older revision		Revision as of 19:15, 18 May 2022
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	One proposal is the synthesis and usage of adamantanes with corners substituted with boron and/or nitrogen.		One proposal is the synthesis and usage of adamantanes with corners substituted with boron and/or nitrogen.
	* Either alternatingly wit 4 nitrogen atoms and 4 boron atoms		* Either alternatingly wit 4 nitrogen atoms and 4 boron atoms
	* Or two different molecules. <br>One with all 8 substituted with nitrogen (adamanzane). <br>The other one with all 8 substituted with boron.		* Or two different molecules. <br>One with all 8 substituted with nitrogen (adamanzane aka 1,3,5,7-tetraazaadamantane). <br>The other one with all 8 substituted with boron (??? aka 1,3,5,7-tetraboroadamantane).

	The idea is {{wikitodo\|verify that}} that unlike open carbon bonds (carbon radicals)<br>		The idea is {{wikitodo\|verify that}} that unlike open carbon bonds (carbon radicals)<br>

Apm: /* External links */ added section === Adamantane related work === with some links

2022-05-18T17:10:13Z

External links: added section === Adamantane related work === with some links

← Older revision		Revision as of 19:10, 18 May 2022
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	== External links ==		== External links ==

			=== Adamantane related work ===

			'''Awesome graphics''' thereto (and coupling to nanotubes) on
			[https://www.somewhereville.com/the-design-of-carbon-nanotube-based-dative-structures-from-supramolecular-principles/ www.somewhereville.com]

			* 2020 Complexes Between Adamantane Analogues B4X6 -X = {CH2, NH, O ; SiH2, PH, S} - and Dihydrogen, B4X6:nH2 (n = 1–4)<br>[https://www.mdpi.com/1420-3049/25/5/1042/htm at www.mdpi.com]
			* 2018 Adamantane-Derived Carbon Nanothreads: High Structural Stability and Mechanical Strength<br>[https://pubs.acs.org/doi/10.1021/acs.jpcc.7b12603 at pubs.acs.org]
			* 2009 '''Functionalized adamantane: Building blocks for nanostructure self-assembly''' <br>[https://journals.aps.org/prb/abstract/10.1103/PhysRevB.80.125421 at journals.aps.org]
			* 2008 Electronic nature of the aromatic adamantanediyl ions and its analogues <br>[https://www.scielo.br/j/jbchs/a/dpYfcxt9bTjhWfdTWf8CCRJ/?format=html&lang=en# at www.scielo.br]

	=== Wikipedia ===		=== Wikipedia ===

Apm: /* Related */

2022-05-18T14:08:49Z

← Older revision		Revision as of 16:08, 18 May 2022
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	== Related ==		== Related ==

			* The "[[downward inward]]" aspect of: [[Expanding the kinematic loop]]
	* [[Stiffness]]		* [[Stiffness]]
	* [[Combining advantages of different selfassembly technologies]]		* [[Combining advantages of different selfassembly technologies]]

Apm: /* Spiroligomers */

2022-05-18T14:06:50Z

Spiroligomers

← Older revision		Revision as of 16:06, 18 May 2022
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	== Examples ==		== Examples ==

	=== [[Spiroligomers]] ===		=== Spiroligomers ===

	These are:		These are:
	* typically 2D polycyclic		* typically 2D polycyclic
	* do not allow for any rotational degrees of freedom		* do not allow for any rotational degrees of freedom

			See main page: [[Spiroligomers]]

	=== Adamantane related building blocks ===		=== Adamantane related building blocks ===

Apm: /* Spiroligomers */

2022-05-18T14:06:19Z

Spiroligomers

← Older revision		Revision as of 16:06, 18 May 2022
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	== Examples ==		== Examples ==

	=== Spiroligomers ===		=== [[Spiroligomers]] ===

	~~'''[[Spiroligomers]].~~ These are:~~'''~~		These are:
	* typically 2D polycyclic		* typically 2D polycyclic
	* do not allow for any rotational degrees of freedom		* do not allow for any rotational degrees of freedom