Difference between revisions of "Direct path"

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The ''direct path'' is a second [[Pathways to advanced APM systems|pathway to advanced APM systems]] beside the [[incremental path]].
 
The ''direct path'' is a second [[Pathways to advanced APM systems|pathway to advanced APM systems]] beside the [[incremental path]].
  
The objective of the direct path is to attain APM capabilities without the detour over bio-derived and solution phase systems (Skipping directly to [[technology level III]]).
+
The objective of the direct path is to attain APM capabilities without the detour over bio-derived and solution phase systems (Skipping directly to [[technology level III|vacuum gemstone metamaterial technology]]).
  
 
One driving aspect are products that are perceived to be potentially profitable in a relative short term.
 
One driving aspect are products that are perceived to be potentially profitable in a relative short term.
Line 13: Line 13:
  
 
* relatively slow progression of miniaturization of [[scanning probe microscopy|SPM]] and consequently ...
 
* relatively slow progression of miniaturization of [[scanning probe microscopy|SPM]] and consequently ...
* ... little increase of speed at which scanning probe microscopes (SPMs) with [[atomic resolution]] can operate.
+
* ... little increase of speed at which [[scanning probe microscopy|scanning probe microscopes (SPMs)]] with [[positional atomic precision]] can operate.
 
* except very view hard to find instances there there are barely any attempts of miniaturizing UHV vacuum systems {{todo| add links to UHV miniaturization attempts}}
 
* except very view hard to find instances there there are barely any attempts of miniaturizing UHV vacuum systems {{todo| add links to UHV miniaturization attempts}}
 
* Due to very little control of the tip apex structure and even less of the rest of the tips conical widening behind multi-tip-interactions (anything going beyond surface-to-tip-interaction like tip-tip or tip-surface-tip or tip-tip-tip) is still far out of reach.
 
* Due to very little control of the tip apex structure and even less of the rest of the tips conical widening behind multi-tip-interactions (anything going beyond surface-to-tip-interaction like tip-tip or tip-surface-tip or tip-tip-tip) is still far out of reach.
 
* very poor handling of steps bigger than a single atom (slow response z control + z drift) => crashes in up-steps - "shadows" in down-steps
 
* very poor handling of steps bigger than a single atom (slow response z control + z drift) => crashes in up-steps - "shadows" in down-steps
  
Low speed, relatively bad vacuum and high error rate leads to the necessity of keeping the produced atomically precise (and [[atomic resolution|atomically resolving]]) diamondoid designs rather small.
+
Low speed, relatively bad vacuum and high error rate leads to the necessity of keeping the produced atomically precise ([[positional atomic precision|precise in position not only topology]]) diamondoid designs rather small.
  
 
* Restriction to minimal hydrocarbon designs that exclude further chemical elements. See the [[Discussion of proposed nanofactory designs]].
 
* Restriction to minimal hydrocarbon designs that exclude further chemical elements. See the [[Discussion of proposed nanofactory designs]].
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One (maybe rather hard) approach towards [[Technology level III|advanced gem-gum technology]] is to [[skipping technology levels|skip the outlined technology levels]] of the [[incremental path]] and try to create at least one necessarily very small and simple hydrocarbon [[robotic mechanosyntesis core]]** from which via exponential assembly a nanofactory can be spawned.
 
One (maybe rather hard) approach towards [[Technology level III|advanced gem-gum technology]] is to [[skipping technology levels|skip the outlined technology levels]] of the [[incremental path]] and try to create at least one necessarily very small and simple hydrocarbon [[robotic mechanosyntesis core]]** from which via exponential assembly a nanofactory can be spawned.
  
This proto-linkage/proto-manipulator approach is conceptually very near the early naive and '''now obsolete''' since hard-to-access inefficient and undesirable [[molecular assembler|proto-assembler]] concept. The far opposite end of the spectrum complementary to the (equally bad) completely non-directed far too slow "reach gem-gum-tec by accident" extreme end of the [[incremental path]].
+
This proto-linkage/proto-manipulator approach is conceptually very near the early naive and '''now obsolete''' since hard-to-access inefficient and undesirable [[molecular assembler|proto-assembler]] concept. The far opposite end of the spectrum complementary to the (maybe equally bad) completely non-directed far too slow "reach gem-gum-tec by accident" extreme end of the [[incremental path]].
  
 
A little less ambitious but still very challenging approach would be to improve MEMS SPM technology so far that it is fast and accurate enough that arrays of it are able to produce early atomically precise productive nanosystems in sufficiently massive parallelism for early very low throughput products.
 
A little less ambitious but still very challenging approach would be to improve MEMS SPM technology so far that it is fast and accurate enough that arrays of it are able to produce early atomically precise productive nanosystems in sufficiently massive parallelism for early very low throughput products.
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That is instead of using MEMS to pick and place atoms in the future it might be used to pick and place bigger assemblies form [[structural DNA nanotechnology]] de-novo protein technology or similar.
 
That is instead of using MEMS to pick and place atoms in the future it might be used to pick and place bigger assemblies form [[structural DNA nanotechnology]] de-novo protein technology or similar.
  
 +
== Benefits from results of direct path development attempts ==
  
== Direct path & Critique with more or less sound basis ==
+
Experiental (and theoretical) proof of principle for far term goal strongly guided [[mechanosynthesis]].
 +
Showing that the [[fat finger problem]] is not a show stopper even with currently available crude blunt tips with barely known structure and the [[sticky finger problem]] is actually not a problem. The "stickyness" helps instead.
 +
 
 +
== Direct path & critique with more or less sound basis ==
  
 
Eric Drexler very early on (soon after his first book "Engines of Creations" EoC) abandoned the idea of the extreme end of the direct path: [[molecular assembler]]s (often also incorrectly referred to as simply [[nanobots]]).
 
Eric Drexler very early on (soon after his first book "Engines of Creations" EoC) abandoned the idea of the extreme end of the direct path: [[molecular assembler]]s (often also incorrectly referred to as simply [[nanobots]]).
Line 56: Line 60:
 
The strong prominence of the extreme end of the direct path twisted into mythologies lead to [[history|rather unproductive critique]] of [[Main Page|Atomically precise manufacturing (APM)]]
 
The strong prominence of the extreme end of the direct path twisted into mythologies lead to [[history|rather unproductive critique]] of [[Main Page|Atomically precise manufacturing (APM)]]
  
Back when this clash happened the [[incremental path]] towards gemstone metamaterial technology (that lies on the other end of the spectrum and which E. Drexler back than has and still mainly refers to) may have seemed very obscure and unfeasible to the scientists. With the recent breakthroughs in structural DNA nanotechnology. This slowly seems to change though.
+
Back when this clash happened the [[incremental path]] towards [[technology level III|gemstone metamaterial technology]] may have seemed very obscure and unfeasible to the scientists.
 +
With the recent breakthroughs in [[structural DNA nanotechnology]] that rapidly go into the regime of diffusion control and suppression this slowly seems to change though.
 +
 
 +
The [[incremental path]] lies on the other end of the development approach spectrum. This was and still is the route Erik K. Drexler strongly prefers. While the direct path may bring some benefits he sees the direct path mostly as a distraction (source book "[[Radical Abundance]]") which's perception has hindered development more than it has helped it. (See [[pathway controversy]])
  
 
== Difficulties ==
 
== Difficulties ==
Line 64: Line 71:
 
* how to isolate specific areas from potentially requited gas phase process steps
 
* how to isolate specific areas from potentially requited gas phase process steps
 
* currently reachable vacuum levels are not quite sufficient - encapsulation of a small working volume is hard
 
* currently reachable vacuum levels are not quite sufficient - encapsulation of a small working volume is hard
* macroscopic afms are accurate enough (when drift compensated on reference points) but too way too slow
+
* macroscopic AFMs are accurate enough (when drift compensated on reference points) but too way too slow
 
* microscopic AFMs/STMs may be fast enough but are not as accurate yet
 
* microscopic AFMs/STMs may be fast enough but are not as accurate yet
 
* coordinating multiple tips is actively researched but barely possible and very slow
 
* coordinating multiple tips is actively researched but barely possible and very slow
Line 75: Line 82:
  
 
'''Furter discussion''' of the individual issues by people knowledgeable in those areas is '''needed'''.
 
'''Furter discussion''' of the individual issues by people knowledgeable in those areas is '''needed'''.
 +
 +
== Current state ==
 +
 +
The most advanced part of the direct path currently (2017-06) seems to be the technolpgy of <br>
 +
"patterned layer epitaxy" aka "patterned atomic layer epitaxy" (patterned ALE) or more specific: hydrogen depassivation lithography (HDL)<br>
 +
(HDL was first demonstrated by Prof. Joe Lyding of University of Illinois at Urbana-Champaign in 1994)
 +
 +
The (at this time published) structures have still high error rates and are mostly two dimensional.
 +
But they are on the strongly covalently bonding target material silicon and made at relatively high temperatures (that is not liquid helium). That is unless structures are not annealed at high temperatures (which current UHV systems often require) undesired surface reconstruction can often be avoided. {{todo|reference the paper that theoretically analyzes surface reconstruction}}
 +
 +
At lower temperatures and with weaker bonding materials (mostly metals)
 +
more advanced atomically precise manupulation has been demonstrated.
 +
A very impressive example is an atomically precise memory {{todo|add link/ref}}
 +
 +
Note that this is all 2D ony !! <br>The incremental path is far ahead in this regard.
  
 
== Build platform size extension ==
 
== Build platform size extension ==
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Still it's hard to say whether the direct path is competitive or not. At least it will certainly contribute in the form of "working down from the other side".
 
Still it's hard to say whether the direct path is competitive or not. At least it will certainly contribute in the form of "working down from the other side".
 
Capability of chemical synthesis of tool-tips for diamondoid [[mechanosynthesis]] (following link suggested) will be very valuable.
 
Capability of chemical synthesis of tool-tips for diamondoid [[mechanosynthesis]] (following link suggested) will be very valuable.
 
== Transmission electron microscopy as atomically precise manipulation tool ==
 
 
Some developments in late 2016 have shown that transmission electron microscopes can be used to convert non atomically precise structures into atomically precise structures. This works only in some specific cases though.
 
 
The usually damaging effect of the imaging electrons is exploited probably in the following way:
 
* The target area is hit strongly localized by the electron beam on high power producing a somehow random result.
 
*The target area is hit strongly localized by the electron beam on low power to check whether the somewhat randomly resulted configuration fits the desired result.
 
* If it does the beam is focused to the next spot expanding the sorted atomically precise area
 
* If it does not not the process is repeated.
 
Some machine learning might be involved for generating the beam in a shape that is most likely to produce the desired result (details not yet clear to the author of these lines).
 
 
* External news link: [http://www.nature.com/news/fire-up-the-atom-forge-1.21017?cookies=accepted Fire up the atom forge] ([https://www.youtube.com/watch?v=CK3Kg9qSdPIhttps://www.youtube.com/watch?v=CK3Kg9qSdPI video]) {{todo| find out some details}}
 
 
The benefit in comparison to [[scanning probe microscopy|SPM]] is that it supposedly works naturally in 3D space.
 
 
Here's a different method that judging from this concept picture [http://www.nature.com/nnano/journal/v9/n6/images/nnano.2014.106-f1.jpg] from "[http://www.nature.com/nnano/journal/v9/n6/full/nnano.2014.106.html?message-global=remove 2D materials: Metallic when narrow]" does allow only very limited control:
 
 
* Related paper: "Directing Matter: Toward Atomic-Scale 3D Nanofabrication." [https://www.ncbi.nlm.nih.gov/pubmed/27183171]
 
* The technique was used in this work: "Flexible metallic nanowires with self-adaptive contacts to semiconducting transition-metal dichalcogenide monolayers" [https://www.ncbi.nlm.nih.gov/pubmed/24776648]
 
  
 
== Related ==
 
== Related ==
  
 
* [[Pathways to advanced APM systems]]
 
* [[Pathways to advanced APM systems]]
 +
* [[Scanning probe microscopy]]
 +
* Can electron beams from transmission electron microscopy be used to do at least low throughput early atomically precise manufacturing? See: "[[Quasi atomically precise techniques]]" for a discussion.
 +
* There was a proposal on syntesizing tooltips for diamondoid mechanosynthesis and growing cone extensions by CVD methods. {{todo|add link -- was it "how to make nanodiamond" ?}} {{todo|check if there was some followup work}}
  
 
== External Links ==
 
== External Links ==
Line 136: Line 141:
 
=== Recently more or less active projects that may focus more on the direct path ===
 
=== Recently more or less active projects that may focus more on the direct path ===
  
* Atoms to Product (A2P) - Darpa [http://www.darpa.mil/program/atoms-to-product]
+
* nano.gov [https://www.nano.gov/node/1900 DOE: Atomically Precise Manufacturing FY 2018] (Some focus on the [[incremental path]] too.)
 
* '''Video:''' (2015-08-5/6) [https://www.youtube.com/watch?v=pFOLYPzstRM&feature=share Proposal for Atomically Precise Manufacturing by the US Department of Energy] [https://www.youtube.com/watch?v=zD0F780x7PM (old dead link 1)]<br> from the [https://energy.gov/eere/amo/downloads/integrated-nanosystems-atomically-precise-manufacturing-workshop-august-5-6-2015 INTEGRATED NANOSYSTEMS FOR ATOMICALLY PRECISE MANUFACTURING WORKSHOP – AUGUST 5-6, 2015] <br> Citation: "The US Department of Energy (DOE) Advanced Manufacturing Office (AMO) hosted a Workshop on Integrated Nanosystems for Atomically Precise Manufacturing (INFAPM) in Berkeley, California, August 5-6, 2015."
 
* '''Video:''' (2015-08-5/6) [https://www.youtube.com/watch?v=pFOLYPzstRM&feature=share Proposal for Atomically Precise Manufacturing by the US Department of Energy] [https://www.youtube.com/watch?v=zD0F780x7PM (old dead link 1)]<br> from the [https://energy.gov/eere/amo/downloads/integrated-nanosystems-atomically-precise-manufacturing-workshop-august-5-6-2015 INTEGRATED NANOSYSTEMS FOR ATOMICALLY PRECISE MANUFACTURING WORKSHOP – AUGUST 5-6, 2015] <br> Citation: "The US Department of Energy (DOE) Advanced Manufacturing Office (AMO) hosted a Workshop on Integrated Nanosystems for Atomically Precise Manufacturing (INFAPM) in Berkeley, California, August 5-6, 2015."
 +
* Atoms to Product (A2P) - Darpa [http://www.darpa.mil/program/atoms-to-product]
 +
* The company zyvex (zyvex LABS) is working more on the direct path end of the spectrum of approaches. <br> Here's [http://www.zyvexlabs.com/apm/rd/science-of-apm/ zyvex's page about Atomically Precise Manufacturing]
 +
 +
=== Direct path seems correlated with military research ===
 +
 +
* University of waterloo about DARPA's older [https://uwaterloo.ca/institute-nanotechnology/research-waterloo-institute-nanotechnology/facilities-equipment/center-integrated-radio-frequency-engineering/tbn-spm tip based nanofabrication (TBN)] program -- funded 2011-2013 (?)
 +
* DARPA's newer "atoms to products" program [http://www.darpa.mil/program/atoms-to-product]
 +
* '''zyvex''' is involved with making nanotube boats for fighting pirates
  
 
=== General discussions that may relate more to the direct path ===
 
=== General discussions that may relate more to the direct path ===
Line 145: Line 158:
 
* [http://www.kurzweilai.net/how-to-make-a-nanodiamond-a-simple-tool-for-positional-diamond-mechanosynthesis-and-its-method-of-manufacture How To Make a Nanodiamond: A Simple Tool for Positional Diamond Mechanosynthesis, and its Method of Manufacture] (January 27, 2006 by Robert A. Freitas Jr.)
 
* [http://www.kurzweilai.net/how-to-make-a-nanodiamond-a-simple-tool-for-positional-diamond-mechanosynthesis-and-its-method-of-manufacture How To Make a Nanodiamond: A Simple Tool for Positional Diamond Mechanosynthesis, and its Method of Manufacture] (January 27, 2006 by Robert A. Freitas Jr.)
 
* [http://www.molecularassembler.com/Papers/PathDiamMolMfg.htm Pathway to Diamond-Based Molecular Manufacturing] (2004-10-22 Robert A. Freitas Jr.)
 
* [http://www.molecularassembler.com/Papers/PathDiamMolMfg.htm Pathway to Diamond-Based Molecular Manufacturing] (2004-10-22 Robert A. Freitas Jr.)
 +
 +
=== Wikipedia ===
 +
 +
* [https://en.wikipedia.org/wiki/Atomic_layer_epitaxy atomic layer epitaxy ALE] aka ALD (needs to be combined with atomically precise patterned depassivation to allow for the creation of atomically precice structures.)
  
  
 
[[Category:General]]
 
[[Category:General]]
 
[[Category:Disquisition]]
 
[[Category:Disquisition]]

Revision as of 16:02, 5 November 2017

Template:Biased

The direct path is a second pathway to advanced APM systems beside the incremental path.

The objective of the direct path is to attain APM capabilities without the detour over bio-derived and solution phase systems (Skipping directly to vacuum gemstone metamaterial technology).

One driving aspect are products that are perceived to be potentially profitable in a relative short term. The incremental path can easily provide such motivation with medical applications that historically have been cash cows. For the direct path in comparison it seems harder to find such catch-pennies for potential investors. Some potential early products here include e.g. Metric standards. (TODO: add more potential early products for the direct path)

There are several hard hurdles where progress seems slow. Like:

  • relatively slow progression of miniaturization of SPM and consequently ...
  • ... little increase of speed at which scanning probe microscopes (SPMs) with positional atomic precision can operate.
  • except very view hard to find instances there there are barely any attempts of miniaturizing UHV vacuum systems (TODO: add links to UHV miniaturization attempts)
  • Due to very little control of the tip apex structure and even less of the rest of the tips conical widening behind multi-tip-interactions (anything going beyond surface-to-tip-interaction like tip-tip or tip-surface-tip or tip-tip-tip) is still far out of reach.
  • very poor handling of steps bigger than a single atom (slow response z control + z drift) => crashes in up-steps - "shadows" in down-steps

Low speed, relatively bad vacuum and high error rate leads to the necessity of keeping the produced atomically precise (precise in position not only topology) diamondoid designs rather small.

  • Restriction to minimal hydrocarbon designs that exclude further chemical elements. See the Discussion of proposed nanofactory designs.
  • Possibly a hydrosilicon design instead of a hydrocarbon design if silicon becomes mechanosynthesizable before carbon.
    Current experimental "high temperature" (70K...300K) mechanosynthesis demonstrations all use silicon. Carbon is still stuck in theory (See papers linked on the page about mechanosynthesis).

One (maybe rather hard) approach towards advanced gem-gum technology is to skip the outlined technology levels of the incremental path and try to create at least one necessarily very small and simple hydrocarbon robotic mechanosyntesis core** from which via exponential assembly a nanofactory can be spawned.

This proto-linkage/proto-manipulator approach is conceptually very near the early naive and now obsolete since hard-to-access inefficient and undesirable proto-assembler concept. The far opposite end of the spectrum complementary to the (maybe equally bad) completely non-directed far too slow "reach gem-gum-tec by accident" extreme end of the incremental path.

A little less ambitious but still very challenging approach would be to improve MEMS SPM technology so far that it is fast and accurate enough that arrays of it are able to produce early atomically precise productive nanosystems in sufficiently massive parallelism for early very low throughput products.

Most realistically though it seems that the direct path will be massively accelerated by opening up and using results of the incremental path. That is instead of using MEMS to pick and place atoms in the future it might be used to pick and place bigger assemblies form structural DNA nanotechnology de-novo protein technology or similar.

Benefits from results of direct path development attempts

Experiental (and theoretical) proof of principle for far term goal strongly guided mechanosynthesis. Showing that the fat finger problem is not a show stopper even with currently available crude blunt tips with barely known structure and the sticky finger problem is actually not a problem. The "stickyness" helps instead.

Direct path & critique with more or less sound basis

Eric Drexler very early on (soon after his first book "Engines of Creations" EoC) abandoned the idea of the extreme end of the direct path: molecular assemblers (often also incorrectly referred to as simply nanobots). There's not a single word about molecular assemblers / nanobots in his technical book (Nanosystems). It's all about the identification of a sensible far term goal based on well understood physics (exploratory engineering) which resulted in the nanofactory concept. There's no complete bootstrapping plan included just a few hints for starting points that where visible back then.

In popular media though the old molecular assembler meme where stuck and furthermore gained its own mythology of omnivoric and evolving synthetic life. In the meantime a slew of researchers had annexed the fund bringing term "nanotechnology" that E.Drexler originally used in his first books to refer to quite different ideas. The researchers did this unknowing of both E. Drexlers work and unknowing or ignorant about the growing media mythologies. When the media began pestering scientists about dystopic mythologies though and they actually where working mostly on stupid (in the sense of their capabilities) nanoparticles they understandably panicked. Fearing loss of funding public uproar and maybe even terrorism.

They traced back the idea starting from the mythologies on the surface back to the still naive ideas in EoC. Already annoyed from the highly unscientific starting point and due to serious scientists time constraints they did not bother to check into the details of E. Drexlers newer more thought out technical work (Nanosystems).

This lead to reactions along the lines of: "Nanobots are far too dangerous but don't worry they are impossible"
Which is (in a perspective of more than a few years) false in several ways:

  • Nanobots are a super-set of the here referred to hypothetical "rouge molecular assemblers". Nanobots include medical nanobots which will become possible pretty much for certain.
  • It seems there might come up motivations for rouge self replicators (not exactly molecular assemblers) and they seem to become possible when the state of the technology will be advanced sufficiently far (far off future).
  • When the time is ripe for rouge self replicators to emerge (as said far off future) they will be far less dangerous than the horror fairy tale depictions. Limits of "techno-ecological" niches; Presence of gradually introduced countermeasures, ...

In short:
The strong prominence of the extreme end of the direct path twisted into mythologies lead to rather unproductive critique of Atomically precise manufacturing (APM)

Back when this clash happened the incremental path towards gemstone metamaterial technology may have seemed very obscure and unfeasible to the scientists. With the recent breakthroughs in structural DNA nanotechnology that rapidly go into the regime of diffusion control and suppression this slowly seems to change though.

The incremental path lies on the other end of the development approach spectrum. This was and still is the route Erik K. Drexler strongly prefers. While the direct path may bring some benefits he sees the direct path mostly as a distraction (source book "Radical Abundance") which's perception has hindered development more than it has helped it. (See pathway controversy)

Difficulties

  • providing resource materials like ethine and germanium source stuck to a surface but close together and near the building site is nontrivial
  • for tool-tip recharge cycles more sites are needed
  • how to isolate specific areas from potentially requited gas phase process steps
  • currently reachable vacuum levels are not quite sufficient - encapsulation of a small working volume is hard
  • macroscopic AFMs are accurate enough (when drift compensated on reference points) but too way too slow
  • microscopic AFMs/STMs may be fast enough but are not as accurate yet
  • coordinating multiple tips is actively researched but barely possible and very slow
  • operation of current UHV system is painstakingly slow - days to weeks
  • patterned layer epitaxy uses a thermodynamic process between de-passivation steps limiting reliability. [to check]
  • with patterned layer epitaxy breaking loose movable parts seems difficult because: it seems hard to create overhangs, controllably breakable sparse tack down bonds and adjacent closely contacting passivated surfaces.
  • replenish-ability
  • harsh CVD conditions (when used)
  • ...

Furter discussion of the individual issues by people knowledgeable in those areas is needed.

Current state

The most advanced part of the direct path currently (2017-06) seems to be the technolpgy of
"patterned layer epitaxy" aka "patterned atomic layer epitaxy" (patterned ALE) or more specific: hydrogen depassivation lithography (HDL)
(HDL was first demonstrated by Prof. Joe Lyding of University of Illinois at Urbana-Champaign in 1994)

The (at this time published) structures have still high error rates and are mostly two dimensional. But they are on the strongly covalently bonding target material silicon and made at relatively high temperatures (that is not liquid helium). That is unless structures are not annealed at high temperatures (which current UHV systems often require) undesired surface reconstruction can often be avoided. (TODO: reference the paper that theoretically analyzes surface reconstruction)

At lower temperatures and with weaker bonding materials (mostly metals) more advanced atomically precise manupulation has been demonstrated. A very impressive example is an atomically precise memory (TODO: add link/ref)

Note that this is all 2D ony !!
The incremental path is far ahead in this regard.

Build platform size extension

On natural crystals atomically flat areas have only limited size. For CVD grown diamond this is even more so than for silicon. The size of facets should at least provide enough space for the assembly of tool-tips. If the capability to form overhangs is present one can build an inverted pyramid (sparsely filled to save time) to gain a perfectly flat surface of grater size.

Two types of DME design

Depending how direct one assumes technology level III is acessible one may choose from two voluntary design restrictions.

Those are A pure hydrocarbon structures (with sparsely included germainum allowed [add ref]) and B structures incorporating various nonmetals for e.g. elegant surface passivations from second and third row of the periodic table.

  • If one assumes skipping of technology levels will succeed first a plethora of pre-existing right of the bat buildable structures will be very helpful.
  • If one assumes incremental technology improvement will lead us further nonmetal including structures can provide a "final goal" sketch
  • in reality somewhat in-between might happen.

Both choices have reason to be made and should probably be followed in parallel.

Relation to the incremental path

Link to the articles "Toward Advanced Nanotechnology:..." from K. Eric Drexlers Blog.

At the beginning of the research and exploratory engineering for advanced APM the hurdle to overcome the barrier to gain mechanosynthetic capabilities in the form of technology level III (the now outdated concept of assemblers was the primary model back then) was underestimated by many. The gap between the nature of biological systems and the nature of the target technology seemed to be too big to bridge in any foreseeable way. Thus by many an approach through direct tip based manufacturing with macro/microscopic tools (and some minimal chemical synthesis) was and still is seen as the primary route to go.

With new developments in the "nature inspired" molecular science department the mentioned gap closed down to a point where the further path became more foreseeable. With "new developments" what is meant here is mainly structural DNA nanotechnology (but also some other areas). This is actually quite far from biology. An "artifibiological" intermediate link one could say.

Still it's hard to say whether the direct path is competitive or not. At least it will certainly contribute in the form of "working down from the other side". Capability of chemical synthesis of tool-tips for diamondoid mechanosynthesis (following link suggested) will be very valuable.

Related

  • Pathways to advanced APM systems
  • Scanning probe microscopy
  • Can electron beams from transmission electron microscopy be used to do at least low throughput early atomically precise manufacturing? See: "Quasi atomically precise techniques" for a discussion.
  • There was a proposal on syntesizing tooltips for diamondoid mechanosynthesis and growing cone extensions by CVD methods. (TODO: add link -- was it "how to make nanodiamond" ?) (TODO: check if there was some followup work)

External Links

Recently more or less active projects that may focus more on the direct path

Direct path seems correlated with military research

  • University of waterloo about DARPA's older tip based nanofabrication (TBN) program -- funded 2011-2013 (?)
  • DARPA's newer "atoms to products" program [2]
  • zyvex is involved with making nanotube boats for fighting pirates

General discussions that may relate more to the direct path

Wikipedia

  • atomic layer epitaxy ALE aka ALD (needs to be combined with atomically precise patterned depassivation to allow for the creation of atomically precice structures.)